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TERT-BUTYL N-(4-BROMOPHENYL)-CARBAMATE

TERT-BUTYL N-(4-BROMOPHENYL)-CARBAMATE Basic information
Product Name:TERT-BUTYL N-(4-BROMOPHENYL)-CARBAMATE
Synonyms:N-(TERT-BUTOXYCARBONYL)-4-BROMOANILINE;N-BOC-4-BROMOANILINE;TERT-BUTYL N-(4-BROMOPHENYL)-CARBAMATE;TERT-BUTYL 4-BROMOPHENYLCARBAMATE;tert-butyl 5-bromopyrazin-2-ylcarbamate;N-BOC-4-bromoaniline, 95+%;4-Bromoaniline, N-BOC protected;(4-Bromophenyl)carbamic acid tert-butyl ester
CAS:131818-17-2
MF:C11H14BrNO2
MW:272.14
EINECS:
Product Categories:Nitrogen Compounds;Organic Building Blocks;Protected Amines;amine|alkyl bromide| carboxylic ester
Mol File:131818-17-2.mol
TERT-BUTYL N-(4-BROMOPHENYL)-CARBAMATE Structure
TERT-BUTYL N-(4-BROMOPHENYL)-CARBAMATE Chemical Properties
Melting point 103-106 °C(lit.)
Boiling point 281.1±23.0 °C(Predicted)
density 1.398
Fp 124℃
storage temp. 2-8°C
pka12.99±0.70(Predicted)
form Powder
color Beige
CAS DataBase Reference131818-17-2(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
Hazard Note Irritant
HS Code 29242990
MSDS Information
ProviderLanguage
SigmaAldrich English
TERT-BUTYL N-(4-BROMOPHENYL)-CARBAMATE Usage And Synthesis
General DescriptionN-(tert-Butoxycarbonyl)-4-bromoaniline is an N-(tert-butyloxycarbonyl) [N-BOC] protected 4-bromo aniline. Due to the presence of BOC protection, it serves as an ideal substrate for Suzuki coupling reactions. It affords biaryls via reaction with pyridine or 3-benzaldehyde boronic acids.
TERT-BUTYL N-(4-BROMOPHENYL)-CARBAMATE Preparation Products And Raw materials
Preparation ProductsN-(TERT-BUTOXYCARBONYL)-3-BROMOANILINE-->BOC-4-ABZ-OH-->3-(4-TERT-BUTOXYCARBONYLAMINO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER-->TERT-BUTYL 4-BROMO-2-CHLOROPHENYLCARBAMATE
N-(1-naphthyl)-N',N'-diethylethylenediamine Benzoic acid, 5-bromo-2-[[(1,1-dimethylethoxy)carbonyl]amino]- (9CI) tert-Butyl N-(4-bromo-2-methylphenyl)carbamate tert-butyl 5-bromoindoline-1-carboxylate TERT-BUTYL N-(4-BROMOPHENYL)-CARBAMATE (3-AMINO-4-BROMO-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER TERT-BUTYL N-(3-BROMOPHENYL)CARBAMATE TERT-BUTYL 4-BROMO-2,6-DIMETHYLPHENYLCARBAMATE BOC-(2S)-INDOLINE(5-BR) CARBOXYLIC ACID TERT-BUTYL 4-BROMONAPHTHALEN-1-YLCARBAMATE (2-AMINO-4-BROMO-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER SPECS AI-942/42302066 N-BIS-BOC-4-BROMO-2-CHLOROANILINE TERT-BUTYL 4-BROMO-2-CHLOROPHENYLCARBAMATE N-BIS-BOC-4-BROMO-2,6-DICHLOROANILINE Carbamic acid, (4-bromo-2-methoxyphenyl)-, 1,1-dimethylethyl ester (9CI) N-Boc-4-Bromo-2-fluoroaniline 4-Bromoaniline
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