ChemicalBook Product Catalog Catalyst and Auxiliary UV absorbers Methyl 2-benzoylbenzoate

Methyl 2-benzoylbenzoate

Methyl 2-benzoylbenzoate Basic information
Product Name:Methyl 2-benzoylbenzoate
Synonyms:O-BENZOYLBENZOIC ACID METHYL ESTER;O-BENZOYL BENZOMETHOXYCARBONYL;OBM;IHT-PI OMBB;methyl 2-phenylcarbonylbenzoate;o-Methyl-benzoyl Benzoate;OMNIRADOMBB;2-(Methoxycarbonyl)benzophenone
CAS:606-28-0
MF:C15H12O3
MW:240.25
EINECS:210-112-3
Product Categories:Aromatic Esters;FINE Chemical & INTERMEDIATES;Industrial/Fine Chemicals;Building Blocks;C12 to C63;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;Functional Materials;Photopolymerization Initiators;C12 to C63;Carbonyl Compounds;Esters;API intermediates;606-28-0
Mol File:606-28-0.mol
Methyl 2-benzoylbenzoate Structure
Methyl 2-benzoylbenzoate Chemical Properties
Melting point 48-53 °C (lit.)
Boiling point 352 °C
density 1,69 g/cm3
vapor pressure 0Pa at 20℃
refractive index 1.5740 (estimate)
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
solubility Insoluble in water
form powder to crystal
color White to Orange to Green
Water Solubility 117.7mg/L at 20℃
InChIKeyNQSMEZJWJJVYOI-UHFFFAOYSA-N
LogP2.8 at 25℃
CAS DataBase Reference606-28-0(CAS DataBase Reference)
NIST Chemistry ReferenceBenzoic acid, 2-benzoyl-, methyl ester(606-28-0)
EPA Substance Registry SystemMethyl o-benzoylbenzoate (606-28-0)
Safety Information
Hazard Codes N
Risk Statements 50/53
Safety Statements 60-61
RIDADR UN 3077 9/PG 3
WGK Germany 3
HS Code 29183000
MSDS Information
ProviderLanguage
2-Benzoyl benzoic acid methyl ester English
SigmaAldrich English
Methyl 2-benzoylbenzoate Usage And Synthesis
Chemical PropertiesWhite or yellowish granule crystals, soluble in alcohol and alkali solution, almost insoluble in water when precipitated in acid.
UsesMethyl 2-benzoylbenzoate is used as an anti-ultraviolet absorber and a preservative for food and beverages.
PreparationMethyl-2-benzoylbenzoate can be synthesized from the reaction between corresponding 2-substituted benzoic acid and thionyl chloride in methanol.
DefinitionChEBI: Methyl 2-benzoylbenzoate is a member of benzophenones.
General DescriptionMethyl-2-benzoylbenzoate is a 2-acylarylcarboxylate. It can undergo asymmetric transfer hydrogenation reaction in propanol in the presence of a Ruthenium catalyst. Methyl-2-benzoylbenzoate is formed as one of the reaction products during the reaction between methyl benzoate and lithium 2,2,6,6-tetramethylpiperidide (LiTMP) at -117°C.
Flammability and ExplosibilityNonflammable
Methyl 2-benzoylbenzoate Preparation Products And Raw materials
Raw materialsThionyl chloride-->Methanol-->2-Biphenylcarboxylic acid
Methyl Benzoic anhydride Methyl 2-benzoylbenzoate Bensulfuron methyl AQUANTRAAL Parathion-methyl METHYL JASMONATE Methyl cinnamate Methyl 4-cyanobenzoate METHYL-4-BENZOYLBENZOATE Kresoxim-methyl METHYL-3-BENZOYLBENZOATE Thiophanate-methyl Emamectin benzoate FATTY ACID METHYL ESTER MIX C8-C22 BENZOICACID METHYL THIOPHENE-2-CARBOXYLATE METHYL OCTADEDANOATE
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