Demosan

Demosan Basic information
Product Name:Demosan
Synonyms:TERSAN SP(R);CHLORONEB PESTANAL;CHLORONEB, 250MG, NEAT;2,5-Dichlorohydroquione dimethyl ether;2,5-dichlorohydroquinone dimethyl ether;chloroneb (bsi,iso,ansi);CHLORNEB;demosan10d
CAS:2675-77-6
MF:C8H8Cl2O2
MW:207.05
EINECS:220-222-3
Product Categories:Aromatics;Fungicides;Pesticides
Mol File:2675-77-6.mol
Demosan Structure
Demosan Chemical Properties
Melting point 133-135°C
Boiling point 268°C
density 1.3354 (rough estimate)
refractive index 1.5537 (estimate)
Fp >100 °C
storage temp. Sealed in dry,Room Temperature
form neat
Water Solubility <0.01 g/100 mL at 23 ºC
BRN 1952749
Stability:Stable.
CAS DataBase Reference2675-77-6(CAS DataBase Reference)
NIST Chemistry Reference1,4-Dichloro-2,5-dimethoxybenzene(2675-77-6)
EPA Substance Registry SystemChloroneb (2675-77-6)
Safety Information
Hazard Codes N
Risk Statements 51/53
Safety Statements 61
RIDADR UN3077 9/PG 3
WGK Germany 2
RTECS CZ4750000
HazardClass 9
PackingGroup III
Hazardous Substances Data2675-77-6(Hazardous Substances Data)
MSDS Information
ProviderLanguage
1,4-Dichloro-2,5-dimethoxybenzene English
Demosan Usage And Synthesis
DescriptionChloroneb was developed by Du Pont de Nemours Co. in 1967. It differs from the compounds described above in that it does not contain nitro-groups. In common with other chlorobenzene fungicides, chloroneb has a low mammalian toxicity and a significant vapor pressure so that it was used as a soil fungicide in the culture of beans, cucumber, and cotton (20). In contrast with the nitrobenzene compounds, Phytophthora spp. are rather sensitive to chloroneb. Pythium spp. vary in sensitivity to chloroneb. Because of its low water solubility, chloroneb is only very weakly systemic (21,22).
Chemical PropertiesColorless crystalline solid. Musty odor
Chemical Propertiesbeige powder
UsesChloroneb-D6 is a labelled analogue of Chloroneb (C370935). Chloroneb is a fungicide that has selective activity against certain fungi (e.g. Mucor and Pythium fungi), and is most commonly used for cotton seedlings and bean plants.
DefinitionChEBI: A dimethoxybenzene that is p-dimethoxybenzene which is substituted by chlorines at positions 2 and 5. A fungicide formerly used as a seed treatment, it is not approved for use in the European Union.
General DescriptionWhite to tan solid or beige powder. Musty odor.
Air & Water ReactionsInsoluble in water.
Reactivity ProfileDemosan is stable at temperatures up to 514° F, in water in the presence of dilute acids or alkalis, and in the common organic solvents. Demosan is subject to microbial decomposition in soil under moist conditions.
Fire HazardDemosan is combustible.
Agricultural UsesFungicide: A systemic fungicide used to control snow mold on turf grass; used on cotton, sugar beets and bean seeds to control seedling disease. Not approved for use in EU countries. Registered for use in the U.S. except California
Trade nameCHLORAXYL® SEED TREATER; DELTA-COAT® II; DEMOSAN®; SOIL FUNGICIDE®-1823; TERSAN® SP; TERRANEB® SP; SOIL FUNGICIDE 1823®
PharmacologyChloroneb is not effective against Fusarium but has a relatively broad spectrum of activity compared with other compounds that are specifically active against oomycetes (24). By controlling Rhizoctonia solani, by seed-piece or in furrow applications, chloroneb increased potato yields in Texas (25).
Potential ExposureAn organochlorine/substituted benzene systemic fungicide used to control snow mold on turf grass; used on cotton, sugar beets and bean seeds to control seedling disease. Not approved for use in EU countries.
ShippingUN2761 Organochlorine pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
IncompatibilitiesMay react with strong oxidizers such as chlorates, peroxides, nitrates, etc
Waste DisposalDo not discharge into drains or sewers. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved landfill.Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Incineration with effluent gas scrubbing is recommended. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.
Demosan Preparation Products And Raw materials
Raw materialsHydrochloric acid-->Diethyl ether-->Hydrogen peroxide-->Acetonitrile-->Sulfuryl chloride-->1,4-Dimethoxybenzene
1,4-DICHLORO-2,5-DIETHOXYBENZENE 4-Chloroanisole Direct Blue 106 3,5-Dimethoxyphenol Demosan 3,4-Dimethoxyphenol Dimethyldimethoxysilane 2,5-DICHLOROHYDROQUINONE Dimefluthrin 3-Chloroanisole Dimethoxybenzene (Trifluoromethoxy)benzene 1-(BENZYLOXY)-2,5-DICHLORO-4-METHOXYBENZENE Phthalates DIRECT BLUE 108 p-Dichlorobenzene REMASTRAL BLUE FFRL 2-Chloroanisole

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