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Fmoc-D-Asparagine

Fmoc-D-Asparagine Basic information
Product Name:Fmoc-D-Asparagine
Synonyms:N-(9-FLUORENYLMETHOXYCARBONYL)-D-ASPARAGINE;N-ALPHA-(9-FLUORENYLMETHOXYCARBONYL)-D-ASPARAGINE;NALPHA-[(9H-FLUOREN-9-YLMETHOXY)CARBONYL]-D-ASPARAGINE;N-ALPHA-(9-FLUORENYLMETHYLOXYCARBONYL)-D-ASPARAGINE;N-ALPHA-FMOC-D-ASPARAGINE;FMOC-D-ASN;FMOC-D-ASN-OH;FMOC-D-ASPARAGINE
CAS:108321-39-7
MF:C19H18N2O5
MW:354.36
EINECS:1533716-785-6
Product Categories:Asparagine [Asn, N];Fmoc-Amino Acids and Derivatives;Amino Acids;Amino Acids (N-Protected);Biochemistry;Fmoc-Amino Acids;Fmoc-Amino acid series
Mol File:108321-39-7.mol
Fmoc-D-Asparagine Structure
Fmoc-D-Asparagine Chemical Properties
Melting point ~185 °C (dec.)
alpha 11.9 º (c=1%, DMF)
Boiling point 678.6±55.0 °C(Predicted)
density 1.362±0.06 g/cm3(Predicted)
refractive index 12 ° (C=1, DMF)
storage temp. Sealed in dry,2-8°C
solubility Soluble in water or 1% acetic acid
pka3.68±0.10(Predicted)
form powder to crystal
color White to Almost white
optical activity[α]20/D +11.9±1.5°, c = 1% in DMF
BRN 8510210
CAS DataBase Reference108321-39-7(CAS DataBase Reference)
Safety Information
Safety Statements 24/25
WGK Germany 3
HS Code 29242100
MSDS Information
ProviderLanguage
SigmaAldrich English
Fmoc-D-Asparagine Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
UsesNα-Fmoc-D-asparagine is an N-Fmoc-protected form of D-Asparagine (A788990). D-Asparagine is an isomer of L-Asparagine (A790005) and is used by bacteria (such as Saccharomyces cerevisiae) as a sole nitrogen source for replication. L-Asparagine is also a competitive inhibitor of staphylococcal L-asparaginase and is used as a reagent to synthesize peptide antibiotics.
Fmoc-D-Asparagine Preparation Products And Raw materials
1,1'-Carbonyldiimidazole FMOC-D-ASPARAGINE-XANTHYL FMOC-D-ASN(MBH)-OH N-alpha-FMOC-Nepsilon-BOC-L-Lysine Fmoc-Asp(OtBu)-OH Fmoc-D-Asparagine ASPARAGINASE FMOC-D-ASPARAGINE(TRITYL),FMOC-D-ASPARAGINE(TRT) Carbonyl iron powder L-Asparagine Nalpha-Fmoc-Ndelta-trityl-L-glutamine L-Fmoc-Aspartic acid alpha-tert-butyl ester NICKEL CARBONYL Nalpha-FMOC-L-Asparagine FMOC-D-ASPARAGINE(MTT) Fmoc FMOC-ASN(TRT)-OPFP N-(9-Fluorenylmethoxycarbonyloxy)succinimide
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