Methyl phenylsulfonylacetate

Methyl phenylsulfonylacetate Basic information
Product Name:Methyl phenylsulfonylacetate
Synonyms:PHENYLSULFONYLACETIC ACID METHYL ESTER;2-(Phenylsulfonyl)acetic acid methyl ester;Methyl phenylsulfonylacetate,97%;Methylphenylsulfonylacetate,98%;(METHOXYCARBONYL)METHYL PHENYL SULFONE;METHYL PHENYLSULFONYLACETATE;METHYL PHENYLSULPHONYLACETATE;METHYL ALPHA-(PHENYLSULFONYL)ACETATE
CAS:34097-60-4
MF:C9H10O4S
MW:214.24
EINECS:
Product Categories:Benzene series;Bioactive Small Molecules;Building Blocks;Cell Biology;Chemical Synthesis;M;Organic Building Blocks;Sulfones;Sulfur Compounds
Mol File:34097-60-4.mol
Methyl phenylsulfonylacetate Structure
Methyl phenylsulfonylacetate Chemical Properties
Melting point 30°C
Boiling point 165 °C/0.05 mmHg (lit.)
density 1.305 g/mL at 20 °C (lit.)
refractive index n20/D 1.535(lit.)
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
form clear liquid to slightly cloudy liquid
Specific Gravity1.282
color Light orange to Yellow to Green
Water Solubility Insoluble in water.
BRN 2051463
InChIKeyNLEAIFBNKPYTGN-UHFFFAOYSA-N
CAS DataBase Reference34097-60-4(CAS DataBase Reference)
Safety Information
Risk Statements 10
Safety Statements 23-24/25-43-36/37/39-15/16
WGK Germany 3
HS Code 29309090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Methyl phenylsulfonylacetate Usage And Synthesis
Chemical Propertiesclear colorless to yellow liquid after melting
UsesMethyl phenylsulfonylacetate has been used in a key step during the synthesis of (-)-hybridalactone, marine eicosanoid isolated from the red alga Laurencia hybrida, in dehydrative alkylation of alcohols under modified Mitsunobu conditions followed by desulfonylation using magnesium, in three step synthesis of 2-(hydroxymethyl)indene.
Methyl phenylsulfonylacetate Preparation Products And Raw materials
PHENYLSULFONYLACETIC ACID ETHYL ESTER Methylparaben Sulfosulfuron ETHYL 3-((4-ETHOXYPHENYL)AMINO)-2-((4-METHYLPHENYL)SULFONYL)PROP-2-ENOATE 3-((4-CHLOROPHENYL)SULFONYL)-6,8-DIIODO-2H-CHROMEN-2-ONE Methyl phenylacetate Methyl phenylsulfonylacetate Bensulfuron methyl METHYL P-TOLUENESULPHONYLACETATE BUTTPARK 52\04-48 ETHYL 2-[(4-CHLOROPHENYL)SULPHONYL]ACETATE ETHYL 2-[(4-METHOXYPHENYL)SULFONYL]ACETATE 3-(PHENYL SULFONYL)ACETYLCOUMARIN Thiophanate-methyl ETHYL-A-(4-ACETAMIDOPHENYLSULFONYL)ACETATE TERT-BUTYL 2-[(4-CHLOROPHENYL)SULFONYL]-2-METHYLPROPANOATE 6,8-DIIODO-3-((4-(TRIFLUOROMETHOXY)PHENYL)SULFONYL)-2H-CHROMEN-2-ONE Tosyl cyanide

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