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| | (S)-Oxiranemethanol Basic information |
| | (S)-Oxiranemethanol Chemical Properties |
| Melting point | 72-73 °C | | Boiling point | 66-67 °C19 mm Hg(lit.) | | alpha | -15 º (neat) | | density | 1.116 g/mL at 20 °C(lit.) | | refractive index | n20/D 1.433(lit.) | | Fp | 178 °F | | storage temp. | -20°C | | solubility | Soluble in chloroform, DMSO and methanol. | | form | Liquid | | pka | 14.62±0.10(Predicted) | | color | Pale yellow | | optical activity | [α]20/D 15°, neat | | BRN | 79783 | | InChIKey | CTKINSOISVBQLD-VKHMYHEASA-N | | CAS DataBase Reference | 60456-23-7(CAS DataBase Reference) | | NIST Chemistry Reference | Oxiranemethanol, (S)-(60456-23-7) |
| | (S)-Oxiranemethanol Usage And Synthesis |
| Chemical Properties | Colorless to light yellow liqui | | Uses | Employed in the synthesis of chiral (E)-allylic alcohol side-chains for introduction into prostacyclin and prostaglandin frameworks by cross-metathesis. | | Definition | ChEBI: (S)-glycidol is a glycidol. It is functionally related to a (S)-1,2-epoxypropane. It is an enantiomer of a (R)-glycidol. | | General Description | Glycidol or 2,3-epoxy-1-propanol is a highly reactive epoxy derivative, which is generally used as a monomer in the preparation of many polymers like polyesters,?polycarbonates,?polyurethanes,?and polyamides. It is also used in the preparation of detergents, rubbers, perfumes, fabric dyes, varnishes, cosmetics, and paints. | | Purification Methods | [S(-)-isomer, § also available on polymer support, has b 49-50o/7mm, 66-67o/19mm, [ ] D -1 5o(neat)], [R(+)-isomer has b 56 -5 6 . 5o/11mm, d 4 1.117, n D 1.429, [ ] D +15o (neat)]. Purify glycidol by fractional distillation. |
| | (S)-Oxiranemethanol Preparation Products And Raw materials |
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