4-Bromobenzyl alcohol

4-Bromobenzyl alcohol Basic information

Product Name:	4-Bromobenzyl alcohol
Synonyms:	4-BROMOBENZYL ALCOHOL;RARECHEM AL BD 0075;P-BROMOBENZYL ALCOHOL;Benzyl alcohol, p-bromo-;4-Brom-benzyl alcohol;Brombenzylalcohol;Benzenemethanol, 4-bromo-;4-BROMOBENZYL ALCOHOL 98%
CAS:	873-75-6
MF:	C7H7BrO
MW:	187.03
EINECS:	212-851-7
Product Categories:	Oxygen Compounds;Benzhydrols, Benzyl & Special Alcohols;Alcohol;Alcohols;Bromine Compounds;C7 to C8
Mol File:	873-75-6.mol

4-Bromobenzyl alcohol Chemical Properties

Melting point	75-77 °C (lit.)
Boiling point	220.79°C (rough estimate)
density	1.3839 (rough estimate)
vapor pressure	0.083Pa at 20℃
refractive index	1.5840 (estimate)
storage temp.	Sealed in dry,Room Temperature
solubility	dioxane: soluble1g/10 mL, clear to faintly turbid, colorless to faintly yellow
pka	14.16±0.10(Predicted)
form	Crystals or Crystalline Powder
color	White to slightly beige
Water Solubility	2.31g/L at 20℃
BRN	1931620
InChIKey	VEDDBHYQWFOITD-UHFFFAOYSA-N
LogP	1.59 at 20℃
CAS DataBase Reference	873-75-6(CAS DataBase Reference)
NIST Chemistry Reference	Benzenemethanol, 4-bromo-(873-75-6)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	24/25
WGK Germany	3
Hazard Note	Irritant
HS Code	29062990

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English
ALFA	English

4-Bromobenzyl alcohol Usage And Synthesis

Chemical Properties	WHITE TO SLIGHTLY BEIGE CRYSTALS OR CRYST. POWDER
Uses	4-Bromobenzyl alcohol was used in the synthesis of: hydroxyl end functionalized, substituted polyfluorene amphiphilic, symmetric rod-coil, triblock copolymer of poly(9,9-didodecylfluorene-2,7-diyl) and poly(hydroxyl ethyl methacrylate)
Synthesis Reference(s)	The Journal of Organic Chemistry, 48, p. 3074, 1983 DOI: 10.1021/jo00166a029 Tetrahedron Letters, 36, p. 3169, 1995 DOI: 10.1016/0040-4039(95)00504-6
General Description	4-Bromobenzyl alcohol undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls. It undergoes oxidation reaction in the presence of polyvinylpolypyrrolidone-supported hydrogen peroxide, silica sulfuric acid and ammonium bromide to yield 4-bromobenzaldehyde. It undergoes efficient trimethylsilylation reaction with 1,1,1,3,3,3-hexamethyldisilazane in the presence of catalytic amount of aspartic acid in acetonitrile.
Flammability and Explosibility	Notclassified

4-Bromobenzyl alcohol Preparation Products And Raw materials

Raw materials	Methanol-->Sodium borohydride-->4-Bromobenzaldehyde
Preparation Products	4-BROMODIPHENYLMETHANE-->4-(TRIMETHYLSILYLETHYNYL)BENZYL ALCOHOL-->4-ETHYNYLBENZYL ALCOHOL 97-->DIETHYL 4-BROMOBENZYL PHOSPHONATE-->(4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)methanol-->p-(phenylthio)benzyl alcohol-->1-Bromo-4-(2,2,2-trifluoroethyl)benzene-->Ethyl 4-bromobenzoate-->1(2H)-Naphthalenone, 6-[(4-bromophenyl)methoxy]-3,4-dihydro-

4-Bromo-2-nitrobenzyl alcohol 2-METHOXY-5-BROMOBENZYL ALCOHOL 2-AMINO-3,5-DIBROMOBENZYL ALCOHOL (S)-α-Methyl-2-bromobenzyl alcohol 3-BROMOBENZYL ALCOHOL,3-Bromobenzyl alcohol 98%,M-BROMOBENZYL ALCOHOL 4-Bromobenzyl alcohol Sulfobromophthalein sodium 3-BROMOBENZYL ALCOHOL, [7-14C] α-Methyl-2-bromobenzyl alcohol Tetrabromo-2-sulfobenzoic acid cyclic anhydride 4-Bromo-1,8-naphthalic anhydride 2,4-Dibromobenzyl Alcohol 2-AMINO-4-BROMOBENZYL ALCOHOL α-(1-Methyl-1H-benzimidazole-2-yl)-4-bromobenzyl alcohol 3-Amino-5-bromobenzyl alcohol (S)-α-Methyl-3-bromobenzyl alcohol 2-Hydroxybenzyl alcohol O-BROMOBENZYL ALCOHOL,2-BROMOBENZYL ALCOHOL 98%,2-BROMOBENZYL ALCOHOL

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