1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE

1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE Basic information
Product Name:1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE
Synonyms:1,6-Anhydro-D-glucopyranose, 99℉;1,6-Anhydro-beta-D-glucopyranose, 99+%;1,6-Anhydro-b-D-glucopyranose;1,6-anhydro-á-d-glucopyranose;1,6-anhydro-beta-glucopyranose;1,6-ANHYDRO-BETA-D-GLUCOPYRA;1,6-ANHYDRO-SS-D-GLUCOPYRANOSE;1,6-Dideoxy-1,6-epoxy-β-D-glucopyranose
CAS:498-07-7
MF:C6H10O5
MW:162.14
EINECS:207-855-0
Product Categories:O-Substituted Sugars;Biochemistry;Sugars, Carbohydrates & Glucosides;Glucose;Sugars;Carbohydrates & Derivatives;Glycon Biochem
Mol File:498-07-7.mol
1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE Structure
1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE Chemical Properties
Melting point 182-184 °C(lit.)
alpha -66 º (C=1 IN H2O)
Boiling point 208.81°C (rough estimate)
density 1.2132 (rough estimate)
refractive index -66.5 ° (C=2, H2O)
storage temp. 2-8°C
solubility Methanol (Slightly), Water (Sparingly)
pka13.40±0.60(Predicted)
form Crystalline Powder or Crystals
color White to slightly beige
optical activity[α]18/D 66°, c = 1 in H2O
Water Solubility Soluble in Ethanol and Water.
BRN 80998
Stability:Hygroscopic
LogP-1.694 (est)
NIST Chemistry Reference1,6-Anhydro-beta-D-glucopyranose(498-07-7)
EPA Substance Registry System.beta.-D-Glucopyranose, 1,6-anhydro- (498-07-7)
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 22-24/25-36-26
WGK Germany 3
HS Code 29400000
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE Usage And Synthesis
Chemical PropertiesWhite Crystalline Odourless Solid
Uses1,6-Anhydrohexopyranoses have proven to be valuable synthons for the preparation of biologically important and structurally diverse products (e.g. rifamycin S, indanomycin, thromboxane B2, (+)-biotin , tetrodotoxin, quinone, and macrolide antibiotics) as well as for modified sugars.
Uses1,6-Anhydro-β-D-glucose is an useful carbohydrate synthon pharmaceutical intermediate.
Uses1,6-Anhydro-beta-D-glucopyranose is used for the preparation of biologically important and structurally diverse products such as rifamycin S, indanomycin, thromboxane B2, (+)-biotin, tetrodotoxin, quinone, macrolide antibiotics and modified sugars. It is used as a chemical tracer for biomass burning in atmospheric chemistry studies, particularly with respect to airborne particulate matter. It aids in the production of bioethanol.
DefinitionChEBI: A anhydrohexose that is the 1,6-anhydro-derivative of beta-D-glucopyranose.
General Description1,6-Anhydro-β-D-glucose (Levoglucosa), belonging to the class of anhydrosugars, is an indicator of the burning of biomass in atmospheric aerosol, snow, and ice. It is formed via pyrolysis of glucans, such as cellulose and starch. Levoglucosa is also found in municipal waste and thermochemical processing products of biomass and soil.
1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE Preparation Products And Raw materials
Preparation Productsβ-D-Glucopyranose, 1,6-anhydro-2,3,4-tris-O-(trimethylsilyl)-
D-Galactose 1,6-ANHYDRO-BETA-D-[UL-13C6]GLUCOSE 1,6-ANHYDRO-BETA-D-[UL-2H7]GLUCOSE 1,6-ANHYDRO-2,3,4-TRI-O-BENZYL-BETA-D-GLUCOPYRANOSE 1,6-ANHYDRO-2,4-DI-O-BENZYL-BETA-D-GLUCOPYRANOSE 1,6-Anhydro-4-O-p-toluenesulfonyl-β-D-glucopyranose 1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE 3,4-DI-O-ACETYL-1,6-ANHYDRO-2-O-P-TOLUENESULFONYL-BETA-D-GLUCOPYRANOSE 1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE, 2,3,4-TRIACETATE,1,6-Anhydro-beta-D-glucopyranose triacetate,1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE-2,3,4-TRI-O-ACETATE 1,6-ANHYDRO-2,4-DI-O-P-TOLUENESULFONYL-BETA-D-GLUCOPYRANOSE DEXTROSE 1,6-ANHYDRO-BETA-D-GLUCOPYRANOSE, 2,3,4-TRIACETATE 1,6-Anhydro-2-O-p-toluenesulfonyl-b-D-glucopyranose 7,8-DIOXABICYCLO[3.2.1]OCTANE-2,3,4-TRIOL

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