ChemicalBook Product Catalog Chemical Reagents Organic reagents Aromatic ketones 4-CYANOBENZOPHENONE

4-CYANOBENZOPHENONE

4-CYANOBENZOPHENONE Basic information
Product Name:4-CYANOBENZOPHENONE
Synonyms:4-CYANOBENZOPHENONE;4-BENZOYLBENZONITRILE;P-CYANOBENZOPHENONE;4-Cyano-benzophenon;Benzonitrile, 4-benzoyl-;benzophenone-4-carbonitrile;4-Cyanobenzophenone,98%
CAS:1503-49-7
MF:C14H9NO
MW:207.23
EINECS:216-126-6
Product Categories:Aromatic Benzophenones & Derivatives (substituted);Building Blocks;C10 to C27;Chemical Synthesis;Cyanides/Nitriles;Nitrogen Compounds;Organic Building Blocks
Mol File:1503-49-7.mol
4-CYANOBENZOPHENONE Structure
4-CYANOBENZOPHENONE Chemical Properties
Melting point 110-114 °C(lit.)
Boiling point 346.25°C (rough estimate)
density 1.1259 (rough estimate)
refractive index 1.4700 (estimate)
storage temp. Sealed in dry,Room Temperature
form solid
color White
Water Solubility Insoluble in water.
BRN 641181
CAS DataBase Reference1503-49-7(CAS DataBase Reference)
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 26-36
RIDADR 3439
WGK Germany 3
HazardClass 6.1
PackingGroup III
HS Code 29269095
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
4-CYANOBENZOPHENONE Usage And Synthesis
Chemical Propertiesslightly yellow crystalline powder
UsesSubstituted benzophenones?are used to determine the quantum yields for norbornadiene(N)?quadricyclane(Q) and Q?N isomerization. It is employed as a triplet sensitizers.
Synthesis Reference(s)The Journal of Organic Chemistry, 41, p. 1187, 1976 DOI: 10.1021/jo00869a023
Tetrahedron Letters, 26, p. 4819, 1985 DOI: 10.1016/S0040-4039(00)94960-8
General Description4-Cyanobenzophenone is a benzophenone derivative that can be prepared by treating 4-cyanobenzoyl chloride with benzene. Its reduction under electrochemical condition led to the formation of 4-t-butyl-benzophenone and 1-(4-cyanophenyl)-2,2-dimthyl-1-phenylpropan-1-ol. Its efficiency as triplet sensitizer for norbornadiene(N)→quadriciane(Q) and Q→N photoisomerization has been assessed.
2-BROMO-4'-CYANOBENZOPHENONE 4-CYANO-4'-MORPHOLINOMETHYL BENZOPHENONE 4-CYANO-4'-PYRROLIDINOMETHYL BENZOPHENONE 4-CYANO-4'-METHOXYBENZOPHENONE 9-OXO-9H-THIOXANTHENE-3-CARBONITRILE-10,10-DIOXIDE 1,4-DIAMINO-2,3-DICYANO-9,10-ANTHRAQUINONE 4-BROMO-4'-CYANOBENZOPHENONE 4-CYANO-4'-PIPERIDINOMETHYL BENZOPHENONE 4-CYANO-2'-IODOBENZOPHENONE 4-CYANO-4'-IODOBENZOPHENONE 4-CYANO-2'-METHOXYBENZOPHENONE 4-CYANO-4'-NITROBENZOPHENONE 4-(4-CYANOBENZOYL)THIOPHENOL 4-CYANO-3'-IODOBENZOPHENONE 4-AZETIDINOMETHYL-4'-CYANOBENZOPHENONE 4-CYANO-4'-[8-(1,4-DIOXA-8-AZASPIRO[4.5]DECYL)METHYL]BENZOPHENONE 4-CYANO-3'-METHOXYBENZOPHENONE 3-BROMO-4'-CYANOBENZOPHENONE
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