SILVER(II) FLUORIDE

SILVER(II) FLUORIDE Basic information
Product Name:SILVER(II) FLUORIDE
Synonyms:SILVER DIFLUORIDE;SILVER(II) FLUORIDE;argentfluorure;ARGENTIC FLUORIDE;silverfluoride(agf2);Silver(ll) fluoride;Silverfluoride2;Silverfluoridebrownpowder
CAS:7783-95-1
MF:AgF2
MW:145.87
EINECS:232-037-5
Product Categories:metal halide;Materials Science;Metal and Ceramic Science;Salts;Silver Salts
Mol File:7783-95-1.mol
SILVER(II) FLUORIDE Structure
SILVER(II) FLUORIDE Chemical Properties
Melting point 690 °C(lit.)
Boiling point 700°C
density 4.57 g/mL at 25 °C(lit.)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Soluble in hexane, chloroform, chlorofluorocarbon and hydrogen fluoride.
form Crystalline
color Brown
Specific Gravity4.7
Water Solubility decomposed by H2O [CRC10]
Sensitive Moisture Sensitive & Hygroscopic
Merck 14,8513
Exposure limitsACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3
CAS DataBase Reference7783-95-1(CAS DataBase Reference)
EPA Substance Registry SystemSilver fluoride (AgF2) (7783-95-1)
Safety Information
Hazard Codes O,T,C
Risk Statements 8-14-23/24/25-34
Safety Statements 17-26-36/37/39-45
RIDADR UN 1759 8/PG 2
WGK Germany 3
RTECS VW4200000
3-8-10
Hazard Note Corrosive
TSCA T
HazardClass 5.1
PackingGroup III
HS Code 28432900
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
SILVER(II) FLUORIDE Usage And Synthesis
Chemical Propertiesdark brownish to dark grey powder
UsesIn the fluorination of hydrocarbons.
UsesSilver(II) fluoride is used as a fluorinating and oxidizing agent. It is also used in the preparation of organic perfluorocompounds and in the fluorination of aromatic compounds. In addition, it is also used in pharmacy and electroplating industry. It serves as an intermediate in the catalysis of gaseous reactions with fluorine by silver. It is utilized in the oxidation of xenon to xenon difluoride.
Safety ProfilePoison by subcutaneous route. Powerful oxidizing agent. hhxtures with boron + water are explosive. When heated to decomposition it emits toxic fumes of F-. See also FLUORIDES and SILVER COMPOUNDS
Purification MethodsIt is highly TOXIC because it liberates HF and F2. It is very hygroscopic and reacts violently with H2O. It is a powerful oxidising agent and liberates O3 from dilute acids, and I2 from I-solution. Store it in quartz or iron ampoules. It is white when pure; otherwise it is brown-tinged. It is thermally stable up to 700o. [Kwasnik in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 241 1963.]
SILVER(II) FLUORIDE Preparation Products And Raw materials
TELLURIUM HEXAFLUORIDE Zinc sulfide SILVER SELENIDE COBALT(III) FLUORIDE Silver iodide Caesium fluoride Calcium fluoride Manganese fluoride Molybdenum trioxide Nickel fluoride Nitrogen trifluoride IRON (II) FLUORIDE Chlorine trifluoride Phosphorus pentoxide Silver fluoride SILVER(II) FLUORIDE Silver SILVER BIFLUORIDE

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