ChemicalBook Product Catalog Organic Chemistry Hydrocarbons and derivatives Acyclic hydrocarbons CIS-1,4-HEXADIENE

CIS-1,4-HEXADIENE

CIS-1,4-HEXADIENE Basic information
Product Name:CIS-1,4-HEXADIENE
Synonyms:CIS-1,4-HEXADIENE;(4Z)-1,4-Hexadiene;(z)-1,4-hexadiene;1,4-Hexadiene, (Z)-;Nsc157585;cis-1,4-Hexadiene >=99.0%;(z)-4-hexadiene;(Z)-CH2=CHCH2CH=CHCH3
CAS:7318-67-4
MF:C6H10
MW:82.14
EINECS:230-783-6
Product Categories:Acyclic;Alkenes;Organic Building Blocks
Mol File:7318-67-4.mol
CIS-1,4-HEXADIENE Structure
CIS-1,4-HEXADIENE Chemical Properties
Melting point -94.9°C (estimate)
Boiling point 65-66 °C (lit.)
density 0.707 g/mL at 20 °C (lit.)
refractive index n20/D 1.415
Fp -46 °C
BRN 1839519
LogP2.910 (est)
Safety Information
Hazard Codes F,Xn
Risk Statements 11-65
Safety Statements 16-62
RIDADR UN 2458 3/PG 2
WGK Germany 3
RTECS MM1997000
MSDS Information
ProviderLanguage
SigmaAldrich English
CIS-1,4-HEXADIENE Usage And Synthesis
General Descriptioncis-1,4-Hexadiene can be synthesized from the cobalt-catalyzed reaction between butadiene and ethylene. The reaction of this hydrocarbon with Fe(CO)5 affords the trans-1,3-hexadiene-iron tricarbonyl complex (I), plus a small amount of the trans,trans-2,4-hexadiene complex(II). Mechanism of the conversion of cis-1,4-hexadiene to trans-2-methyl-1,3-pentadiene, via rearrangement in the presence of a nickel catalyst has been investigated.
CIS-1,4-HEXADIENE Preparation Products And Raw materials
Jasmone 1,4,5,8,9,10-Hexahydroanthracene 4-TRICHLOROMETHYL-4-METHYL-2,5-CYCLOHEXADIENONE 2,5-DIHYDROXY-1,4-BENZOQUINONE 2,4,4,6-TETRABROMO-2,5-CYCLOHEXADIENONE TETRAFLUORO-1,4-BENZOQUINONE 1,2,3,4,5,6-HEXAMETHYLBICYCLO[2.2.0]HEXA-2,5-DIENE 1-METHOXY-1,4-CYCLOHEXADIENE Cyclohexa-1,4-diene Tetrahydroxyquinone GAMMA-TERPINENE DDQ Colchicine 2,3-Dimethoxy-5-methyl-p-benzoquinone Chloranil 1,4-Benzoquinone Chloranilic acid 1-METHYL-1,4-CYCLOHEXADIENE
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