Pentyl nitrite

Pentyl nitrite Basic information
Product Name:Pentyl nitrite
Synonyms:N-PENTYL NITRITE 97+%;AMYL NITRITE;N-Phenyl nitrile;itramyl;1-(Nitrosooxy)pentane;Nitrous acid amyl ester;Pentyl nitrite, 95.0%(GC);n-Pentyl nitrite for synthesis
CAS:463-04-7
MF:C5H11NO2
MW:117.15
EINECS:207-332-7
Product Categories:
Mol File:463-04-7.mol
Pentyl nitrite Structure
Pentyl nitrite Chemical Properties
Boiling point 104-105°C
density 0,86 g/cm3
vapor density 4
vapor pressure 65 hPa (20 °C)
refractive index 1.3880-1.3910
Fp -40°C
storage temp. Store at +2°C to +8°C.
solubility Decomposes in contact with water,Practically insoluble in water
form clear liquid
color Clear, yellowish liquid
Odorpeculiar, ethereal, fruityodor and pungent, aromatic taste
Water Solubility 3.97g/L
Stability:Light Sensitive, Volatile
LogP2.85
CAS DataBase Reference463-04-7(CAS DataBase Reference)
NIST Chemistry ReferenceAmyl nitrite(463-04-7)
EPA Substance Registry SystemAmyl nitrite (463-04-7)
Safety Information
Hazard Codes F,Xn
Risk Statements 11-20/22
Safety Statements 16-24-45-46
RIDADR 1113
WGK Germany 3
RTECS RA1140000
Autoignition Temperature205 °C
HazardClass 3.1
PackingGroup II
HS Code 29209085
Hazardous Substances Data463-04-7(Hazardous Substances Data)
Toxicitymmo-sat 1 mg/plate BSIBAC 56,816,80
MSDS Information
ProviderLanguage
Pentyl nitrite English
Pentyl nitrite Usage And Synthesis
Chemical PropertiesAmyl nitrites are flammable, yellowish liquid with a penetrating, fruity odor.
UsesAmyl Nitrite is used in the treatment of erectile dysfunction.
DefinitionChEBI: A nitrite ester having n-pentyl as the alkyl group.
General DescriptionA clear colorless to yellowish liquid with a fragrant, fruity odor and pungent aromatic taste. Flash point below 73°F. Boiling point 205-210°F (96-99°C). Less dense than water and insoluble in water. Hence floats on water. Vapors are heavier than air. Produces toxic oxides of nitrogen during combustion. Used in medicine and to make other chemicals.
General DescriptionAmyl nitrite, isopentyl nitrite [(CH3)2CHCH2CH2ONO], isa mixture of isomeric amyl nitrites but is principally isoamylnitrite. It may be prepared from amyl alcohol and HNO2 byseveral procedures. Usually, amyl nitrite is dispensed in ampul form and used by inhalation or orally in alcohol solution.Currently, it is recommended for treating cyanide poisoning;although not the best antidote, it does not require intravenousinjections.
Amyl nitrite is a yellowish liquid with an ethereal odor anda pungent taste. It is volatile and inflammable at room temperature.Amyl nitrite vapor forms an explosive mixture in air oroxygen. Inhalation of the vapor may involve definite explosionhazards if a source of ignition is present, as both roomand body temperatures are within the flammability range ofamyl nitrite mixtures with either air or oxygen. It is nearly insolublein water but is miscible with organic solvents. The nitritealso will decompose in valeric acid and nitric acid.
Air & Water ReactionsHighly flammable. Decomposes on exposure to air, light, or water. Many, but not all, will be colorless flammable toxic gases. Insoluble in water. Reaction with moisture in air or with water produces nitric acid.
Reactivity ProfilePentyl nitrite is an oxidizing agent. May begin a vigorous reaction that culminates in a detonation if mixed with reducing agents, including hydrides, sulfides and nitrides.
Health HazardInhalation or ingestion causes flushing of the face, pulsatile headache, disturbing tachycardia, cyanosis (methemoglobinemia), weakness, confusion, restlessness, faintness, and collapse. Contact with eyes or skin causes irritation.
Flammability and ExplosibilityFlammable
Safety ProfileModerately toxic by inhalation and ingestion. Causes flushing of skin, rapid pulse, headache, and fall in blood pressure. Mutation data reported. See also NITRITES and ESTERS. Flammable when exposed to heat or flame or by spontaneous chemical reaction. To fight fire, use alcohol foam. An oxidizing material. Vapors explode when heated. It will react with oxidizing or reducing materials. When heated to decomposition it emits toxic fumes of NOx.
Potential ExposureAmyl nitrite is used to make pharmaceuticals; perfumes, diazonium compounds, and other chemicals.
ShippingUN1993 Flammable liquids, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, Technical Name Required.
IncompatibilitiesVapors may form explosive mixture with air. Slowly decomposes in light, heat, and on contact with water. A strong oxidizer. Contact with reducing agents and easily oxidizable materials may cause fire and explosions. Reported to be an explosion hazard when exposed to air and light. Keep away from alcohols, antipyrine, alkaline materials; alkaline carbonates; potassium iodide; bromides, and ferrous salts. Attacks metals in the presence of moisture.
Waste DisposalIncineration with scrubber to remove nitrogen oxides from the combustion gases.
Pentyl nitrite Preparation Products And Raw materials
Raw materials1-Pentanol
Preparation ProductsCARVONE-->2-(2-AMINO-4-BIPHENYL)PROPIONITRILE-->3,3'-DIETHYLTHIACYANINE IODIDE-->2-Pyrrolidinone
AMYL NITRITE,Amyl Nitrite, Vaporole,amyl nitrite, mixed isomers Pentyl nitrite Isosorbide dinitrate D-ISOSORBIDE DINITRATE Pentobarbital sodium NITRITE ION CHROMATOGRAPHY STANDARD Rosin pentaerythrityl ester N-AMYL NITRATE NITROUS ACID CYCLOHEXYL NITRATE Octylnitrate AKOS BB-9052 Sodium nitrite Calcium nitrite Amyl acetate 2-Ethylhexyl nitrate Teopranitol Pentaerythrityl oleate

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