ChemicalBook Product Catalog Chemical Reagents Organic reagents Boric acid 3-VINYLPHENYLBORONIC ACID

3-VINYLPHENYLBORONIC ACID

3-VINYLPHENYLBORONIC ACID Basic information
Product Name:3-VINYLPHENYLBORONIC ACID
Synonyms:3-VINYLBENZENEBORONIC ACID;3-VINYLPHENYLBORONIC ACID;AKOS BRN-0142;RARECHEM AH PB 0211;styrene-3-boronic acid;3-Vinylphenylbronicacid;3-Ethenylphenylboronic acid;m-Vinylbenzeneboronic acid
CAS:15016-43-0
MF:C8H9BO2
MW:147.97
EINECS:604-722-2
Product Categories:Boronic acids;Aryl;Boronic Acids;Boronic Acids and Derivatives
Mol File:15016-43-0.mol
3-VINYLPHENYLBORONIC ACID Structure
3-VINYLPHENYLBORONIC ACID Chemical Properties
Melting point 141-147 °C
Boiling point 320.2±35.0 °C(Predicted)
density 1.09±0.1 g/cm3(Predicted)
storage temp. 2-8°C
form powder or crystals
pka8.34±0.10(Predicted)
BRN 3030426
CAS DataBase Reference15016-43-0(CAS DataBase Reference)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-22
Safety Statements 26-36-37/39
RIDADR UN 2811 6.1/PG 3
WGK Germany 3
Hazard Note Irritant
HS Code 2931900090
MSDS Information
ProviderLanguage
ALFA English
3-VINYLPHENYLBORONIC ACID Usage And Synthesis
Usessuzuki reaction
UsesReactant involved in:
  • Suzuki-Miyaura reactions
  • Molecular imprinting of fructose and pinacol
  • Synthesis of arylmercapturic acids via Chen-Lam-Evans arylation
  • Three-component cross-coupling yeilding diarylketones
  • Generation of acyl anion equivalents
General DescriptionMay contain varying amounts of anhydride.
Purification MethodsThis binder for paper or glass crystallises in white plates from H2O (m 144-145o), and its IR has max 919 and 995 (CH2CH=CH2), 1350 (B-O) and 3220 (OH) cm-1 . The dibromo derivative crystallises in white needles from H2O with m 196-197.5o. [Wesley & Rush J Org Chem 27 2598 1962, Beilstein 16 III 1279, 16 IV 1677.]
3-VINYLPHENYLBORONIC ACID Preparation Products And Raw materials
Preparation ProductsBenzenepropanoic acid, 3-ethenyl-
4-Vinylphenylboronic acid MIDA ester TRANS-4-(BETA-NITROVINYL)BENZENEBORONIC ACID 3-VINYLPHENYLBORONIC ACID 3-(3-BORONOPHENYL)ACRYLONITRILE [3-(E-3-METHOXY-3-OXO-1-PROPEN-1-YL)PHENYL]BORONIC ACID 3-((E)-3-ETHOXY-3-OXO-1-PROPEN-1-YL)BENZENEBORONIC ACID 98 3-(2,2-Dicyanovinyl)phenylboronic acid 2-VINYLPHENYLBORONIC ACID 3-(2-CARBOXYVINYL)BENZENEBORONIC ACID E-PHENYLETHENYLBORONIC ACID 4-VINYLPHENYLBORONIC ACID Benzocyclobutene-4-boronic acid 3-[(E)-2-NITROVINYL]PHENYLBORONIC ACID
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