Palladium(II) oxide

Palladium(II) oxide Basic information
Product Name:Palladium(II) oxide
Synonyms:PALLADIUM MONOXIDE;PALLADIUM(II) OXIDE;PALLADIUM OXIDE;PALLADIUM(+2)OXIDE;Palladium oxide pdo;palladiumoxide(pdo);Palladiumoxideblackpowder;Pd87%Palladium(II oxide
CAS:1314-08-5
MF:OPd
MW:122.42
EINECS:215-218-3
Product Categories:metal oxide;chemical reaction,pharm,electronic,materials;Catalysis and Inorganic Chemistry;Homogeneous Pd CatalystsMetal and Ceramic Science;Oxides;Palladium;Inorganics;1314-08-5
Mol File:1314-08-5.mol
Palladium(II) oxide Structure
Palladium(II) oxide Chemical Properties
Melting point 870 °C(lit.)
density 8.7 g/mL at 25 °C(lit.)
RTECS RT3592900
storage temp. Store below +30°C.
form Viscous Liquid
Specific Gravity8.7
color Gray to black
OdorOdorless
Water Solubility practically insoluble
Merck 14,6993
InChIKeyHBEQXAKJSGXAIQ-UHFFFAOYSA-N
CAS DataBase Reference1314-08-5(CAS DataBase Reference)
NIST Chemistry ReferencePalladium oxide(1314-08-5)
EPA Substance Registry SystemPalladium oxide (PdO) (1314-08-5)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
RIDADR 1479
WGK Germany 3
TSCA Yes
PackingGroup II
HS Code 28439090
MSDS Information
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Palladium(II) oxide Usage And Synthesis
Chemical Propertiesgrey to black powder
Physical propertiesGreenish black tetragonal crystals; density 8.3 g/cm3; decomposes to Pd metal at 750°C; insoluble in water and acids; slightly soluble in aqua regia.
UsesCatalytic reduction, in organic synthesis.Palladium(II) oxide is used as a catalyst for reduction in organic synthesis. It is an excellent gas sensing material for carbon monoxide at low working temperatures. It is also used in the preparation of good optical quality films. It is involved in the preparation of LuPd2O4 , which is used in superconducting materials.
UsesPalladium(II) oxide is used to prepare palladium catalyst for hydrogenation. The oxide is readily reduced by hydrogen to metal.
UsesReduction catalyst in synthesis of organic Compounds.
PreparationPalladium(II) oxide is prepared by heating palladium sponge in oxygen at 350°C. The oxide is obtained as a black powder. The oxide also may be prepared specially for catalytic use by heating a mixture of palladium chloride and potassium nitrate at 600°C and then leaching out water-soluble residue. A hydrated form of the oxide, which is acid soluble can be prepared by precipitation from solution, for example, by hydrolysis of palladium nitrate. The brown hydrated oxide converts to black anhydrous oxide on heating. Its solubility in acids decreases with lowering of water content.
Flammability and ExplosibilityNotclassified
Palladium(II) oxide Preparation Products And Raw materials
Preparation ProductsALPHA-D-GLUCOPYRANOSE 1-PHOSPHATE DIPOTASSIUM SALT HYDRATE-->Masoprocol
Gadolinium oxide Terbium Oxide Titanium dioxide Palladium hydroxide Zinc oxide PALLADIUM(II) OXIDE Magnesium oxide CARBON MONOXIDE Palladium(II) oxide ETHYLENE OXIDE (Diethoxymethyl)diphenylphosphine oxide Iron oxide Potassium bis(oxalato)palladate(II) dihydrate, Premion, 99.99% (metals basis) NITRIC OXIDE Palladium NITROUS OXIDE LAURYL DIMETHYLAMINE OXIDE POTASSIUM BIS(OXALATO)PALLADATE (II)

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