Benzylchloromethyl ether

Benzylchloromethyl ether Basic information
Product Name:Benzylchloromethyl ether
Synonyms:(CHLOROMETHOXYMETHYL)BENZENE;Benzene, [(chloromethoxy)methyl]-;(Chloromethoxymethyl)benzene, Benzyloxymethyl chloride;Benzyl chloromethyl ether ,98%;α-Chloromethoxytoluene;Benzyl chloromethyl ether,75%;Benzyl chloroMethyl ether, 75% 50GR;Benzyl chloromethyl ether ,95%
CAS:3587-60-8
MF:C8H9ClO
MW:156.61
EINECS:628-927-1
Product Categories:Building Blocks;C8;Chemical Synthesis;Ethers;Organic Building Blocks;Oxygen Compounds
Mol File:3587-60-8.mol
Benzylchloromethyl ether Structure
Benzylchloromethyl ether Chemical Properties
Boiling point 102 °C/14 mmHg (lit.)
density 1.126 g/mL at 20 °C (lit.)
refractive index n20/D 1.527
Fp 91 °C
storage temp. 2-8°C
solubility Chloroform (Sparingly), Ethyl Acetate (Slightly)
form Liquid
color Clear colorless to pale yellow
Water Solubility Soluble in water [2.7 g/L (25 C)]
BRN 1364034
Stability:Moisture Sensitive, Toxic
InChIKeyLADPCMZCENPFGV-UHFFFAOYSA-N
CAS DataBase Reference3587-60-8(CAS DataBase Reference)
NIST Chemistry ReferenceBenzyl chloromethyl ether(3587-60-8)
Safety Information
Hazard Codes T,Xn,N
Risk Statements 45-22-23-37/38-41-48/22-36/37/38-20/21/22-50-43
Safety Statements 53-26-39-45-36/37/39-36-61
RIDADR UN 2810 6.1/PG 3
WGK Germany 3
19-21
HazardClass 6.1(b)
PackingGroup III
HS Code 29093090
MSDS Information
ProviderLanguage
Benzylchloromethyl ether English
SigmaAldrich English
ACROS English
Benzylchloromethyl ether Usage And Synthesis
Chemical PropertiesColorless liquid
UsesBenzyl chloromethyl ether is employed in the introduction of benzoyloxy- and hydroxymethyl groups.
Synthesis Reference(s)Synthesis, p. 762, 1983 DOI: 10.1055/s-1983-30506
Benzylchloromethyl ether 1,4-bis(chloromethoxymethyl)benzene Chloromethyl methyl ether C8E3 Calcium chloride Phenylacetone Ethylbenzene Chloromethyl ethyl ether Diethyl ether Ammonium chloride Mepiquat chloride Benzyl BIS(CHLOROMETHYL)ETHER Benzyl acetate Dimethyl ether Allylbenzene 2-​[[(2-​ethylphenyl)​(2-​hydroxyethyl)​amino]​methyl]​-​3,​3-​difluoro-Propanenitrile BENZYL GLYCIDYL ETHER

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