Hexahydro-4-methylphthalic anhydride

Hexahydro-4-methylphthalic anhydride Basic information
Product Name:Hexahydro-4-methylphthalic anhydride
Synonyms:HEXAHYDRO-4-METHYLPHTHALIC ANHYDRIDE;HEXAHYDRO-3-METHYLPHTHALIC ANHYDRIDE;3-METHYL-1,2-CYCLOHEXANEDICARBOXYLIC ANHYDRIDE;4-METHYL-1,2-CYCLOHEXANEDICARBOXYLIC ANHYDRIDE;4-METHYLCYCLOHEXANE-1,2-DICARBOXYLIC ANHYDRIDE;3-Isobenzofurandione,hexahydro-5-methyl-1;4-methylcyclohexyl-1,6-dicarboxylicacidanhydride;5-Methylhexahydro-1,3-isobenzofurandione
CAS:19438-60-9
MF:C9H12O3
MW:168.19
EINECS:243-072-0
Product Categories:Organics
Mol File:19438-60-9.mol
Hexahydro-4-methylphthalic anhydride Structure
Hexahydro-4-methylphthalic anhydride Chemical Properties
Melting point -29°C
Boiling point 120°C (1 mmHg)
density 1.162 g/mL at 25 °C(lit.)
vapor pressure 0.23Pa at 25℃
refractive index n20/D 1.477(lit.)
Fp >230 °F
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
pka4.24[at 20 ℃]
form Liquid
color Clear
Water Solubility REACTS
Sensitive Moisture Sensitive
Stability:Hygroscopic, Moisture Sensitive
InChIKeyFKBMTBAXDISZGN-UHFFFAOYSA-N
LogP-3.95 at 20℃
CAS DataBase Reference19438-60-9(CAS DataBase Reference)
EPA Substance Registry System1,3-Isobenzofurandione, hexahydro-5-methyl- (19438-60-9)
Safety Information
Hazard Codes Xn
Risk Statements 41-42/43
Safety Statements 22-24-26-37/39
WGK Germany 1
Hazard Note Irritant
TSCA Yes
HS Code 29172090
MSDS Information
ProviderLanguage
MHHPA English
SigmaAldrich English
ACROS English
ALFA English
Hexahydro-4-methylphthalic anhydride Usage And Synthesis
DescriptionMethylhexahydrophthalic anhydride (MHHP A) is an epoxy hardener, irritant to skin and mucus membranes. It is included in non-diglycidyl-ether-of-bisphenol- A epoxy resins. It can induce both allergic contact dermatitis and immunologic contact urticaria. MHHP A is structurally close to methyltetrahydrophthalic anhydride (MTHP A), which can also cause sensitization.
Chemical PropertiesHexahydro-4-methylphthalic anhydride has a melting point of 29 °C, so it is a liquid at room temperature. It has a boiling point of 120 °C and at 25 °C its density is 1.162 g/mL.
UsesHexahydro-4-methylphthalic anhydride, mixture of?cis?and?trans may be used as an analytical standard for the determination of the analyte in human biological samples by gas chromatography-mass spectrometry (GC-MS).
General DescriptionMethylhexahydrophthalic anhydride, a congener of phthalic anhydride, is utilized in the production of plastics, paints, and electronic components. It can potentially result in allergenic effects on humans upon exposure and cause immunological reactions.
Flammability and ExplosibilityNonflammable
Contact allergensMethylhexahydrophthalic anhydride is an epoxy hardener, irritant to skin and mucous membranes. It is included in nondiglycidyl-ether-of-bisphenol-A epoxy resins. It can induce both allergic contact dermatitis and immunologic contact urticaria. It is structurally close to methyltetrahydrophthalic anhydride, which can also cause sensitization.
Hexahydro-4-methylphthalic anhydride Preparation Products And Raw materials
HEXAHYDRO-3-METHYLPHTHALIC ANHYDRIDE,HEXAHYDRO-3-METHYLPHTHALIC ANHYDRIDE 4-Methylphthalic anhydride SALOR-INT L160776-1EA Methyl HEXAHYDRO-3-METHYLPHTHALIC ANHYDRIDE (3-METHYL-1,2-CYCLOHEXANEDICARBOXYLIC ANHYDRIDE) 8-PHENYL-4-OXA-TRICYCLO[5.2.1.0(2,6)]DECANE-3,5-DIONE 1,14-DIMETHYL-4,10-DIOXATETRACYCLO[5.5.2.0(2,6).0(8,12)]TETRADEC-13-ENE-3,5,9,11-TETRAONE 4-TRANS-PHENYLCYCLOHEXANE-(1R,2-CIS)-DICARBOXYLIC ANHYDRIDE cis-1,2,3,6-Tetrahydrophthalic anhydride hexahydro-1-methylphthalic anhydride ,hexahydro-1-methylphthalic anhydride Bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acid dianhydride 4,7-Epoxyisobenzofuran-5-carboxylic acid, octahydro-1,3-dioxo-, (3a-al pha,4-beta,5-alpha,7-beta,7a-alpha)- 5-endo-(Ethoxycarbonyl)endothall anhydride SALOR-INT L160520-1EA AKOS 92453 Hexahydrophthalic anhydride AKOS 90148 Methyl tetrahydrophthalic anhydride

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