4-BROMOBENZOPHENONE

4-BROMOBENZOPHENONE Basic information
Product Name:4-BROMOBENZOPHENONE
Synonyms:P-BROMOBENZOPHENONE;4-BROMOBENZOPHENONE;LABOTEST-BB LT00053402;(4-bromophenyl)phenyl-methanon;4-bromo-benzophenon;4-bromophenylphenylketone;Benzophenone, 4-bromo-;p-benzoylbromobenzene
CAS:90-90-4
MF:C13H9BrO
MW:261.11
EINECS:202-024-9
Product Categories:C13 to C14;Carbonyl Compounds;Ketones;Aromatic Benzophenones & Derivatives (substituted)
Mol File:90-90-4.mol
4-BROMOBENZOPHENONE Structure
4-BROMOBENZOPHENONE Chemical Properties
Melting point 79-84 °C(lit.)
Boiling point 350 °C(lit.)
density 1.4245 (rough estimate)
refractive index 1.5130 (estimate)
Fp 350°C
storage temp. Sealed in dry,Room Temperature
form Crystalline Powder
color White to light beige
Water Solubility Insoluble in water but slightly soluble in other solvents such as ethanol, ether and benzene.
BRN 1910182
InChIKeyKEOLYBMGRQYQTN-UHFFFAOYSA-N
CAS DataBase Reference90-90-4(CAS DataBase Reference)
EPA Substance Registry System4-Bromobenzophenone (90-90-4)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 37/39-26
WGK Germany 3
RTECS DJ0350000
HS Code 29147000
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
4-BROMOBENZOPHENONE Usage And Synthesis
Chemical PropertiesWHITE TO LIGHT BEIGE CRYSTALLINE POWDER
Uses4-Bromobenzophenone is used in analytical applications such as HPLC and GC. It is also used as a chemical reagent and pharmaceutical intermediate.
Synthesis Reference(s)The Journal of Organic Chemistry, 31, p. 2708, 1966 DOI: 10.1021/jo01346a526
Tetrahedron Letters, 27, p. 929, 1986 DOI: 10.1016/S0040-4039(00)84140-4
Purification MethodsCrystallise the phenone from EtOH. The 2,4-dinitrophenylhydrazone forms orange-red leaflets from dioxane/EtOH with m 207-209o. [Allen & Van Allan J Am Chem Soc 66 7 1944, Beilstein 7 H 422, 7 III 2079, 7 IV 1378.]
4'-BROMO-4-IODOBENZOPHENONE 4-BROMO-2'-CARBOETHOXYBENZOPHENONE 4-BROMO-4'-METHOXYBENZOPHENONE 4-BROMO-3',4'-DIMETHYLBENZOPHENONE (4-BROMO-PHENYL)-(4-TRIFLUOROMETHOXY-PHENYL)-METHANONE Disperse Blue 81 1-Amino-2-bromo-4-hydroxy-9,10-anthraquinone 2-AMINO-3-BROMO-9-FLUORENONE 4-BROMO-4'-METHYLBENZOPHENONE 2-BROMO-3-METHYLANTHRAQUINONE 3-BROMO-4'-ETHOXYBENZOPHENONE 97 (7-BROMO-2,3-DIHYDRO-1,4-BENZODIOXIN-6-YL)(4-BROMOPHENYL)METHANONE 3,4'-DIBROMOBENZOPHENONE 2,4'-DIBROMOBENZOPHENONE 2(4-BROMOBENZOYL)BENZOIC ACID 1,5-diamino-2,4,6,8-tetrabromoanthraquinone (8-BROMO-3,4-DIHYDRO-2H-1,5-BENZODIOXEPIN-7-YL)(4-BROMOPHENYL)METHANONE Disperse Blue 56

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