1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate

1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Basic information
Product Name:1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
Synonyms:(+/-)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE;1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE;(+/-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE;2-HYDROXY-2LAMBDA5-DINAPHTHO[2,1-D:1,2-F][1,3,2]DIOXAPHOSPHEPIN-2-ONE;4-Hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin 4-oxide;(R)-(-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE;(R)-4-HYDROXY DINAPHTHO[2,1-D:1',2'-F][1,3,2]-DIOXAPHOSPHEPIN-4-OXID;(R)-4-HYDROXYDINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE
CAS:35193-63-6
MF:C20H13O4P
MW:348.29
EINECS:252-425-8
Product Categories:Achiral Phosphine;Aryl Phosphine;chiral;Phosphorus Catalysts;Catalysis and Inorganic Chemistry;Phosphorus Compounds
Mol File:35193-63-6.mol
1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Structure
1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Chemical Properties
Melting point ≥300 °C
Boiling point 619.5±38.0 °C(Predicted)
density 1.49±0.1 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
pka1.14±0.20(Predicted)
form Solid
color White to Yellow to Orange
Water Solubility Extremely low soluble in water.
CAS DataBase Reference35193-63-6(CAS DataBase Reference)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-20/21/22
Safety Statements 26-36-36/37/39-22
WGK Germany 3
RTECS RZ2475100
10-23
HS Code 2931499090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
Uses1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, is used as a chiral chemical compound, a chiral ligand used in hydrocarboxylation reactions. Complexes with rhodium and mediates the asymmetric dipolar cycloaddition of diazo compounds. A number of racemic amines which have proven difficult to separate have been resolved with this chiral acid. Palladium derivatives have been used in asymmetric hydrocarboxylations, and rhodium derivatives have been used in dipolar cycloadditions.
1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Preparation Products And Raw materials
1,1'-Bi-2-naphthol 1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Water treatment agent POE ETHYLENE OXIDE (S)-(+)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHYL)PHENYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% (Diethoxymethyl)diphenylphosphine oxide Iron oxide Zinc oxide (R)-TRIP, (11bR)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (R)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate NITRIC OXIDE (S)-(-)-1,1'-Bi-2-naphthol Rutile NITROUS OXIDE (R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95% Clindamycin phosphate (R)-NP-NAP Magnesium oxide SULPHOSUCCINIC ACID ESTER

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