Ethyl 2-(4-phenoxyphenoxy)ethylcarbamate

Ethyl 2-(4-phenoxyphenoxy)ethylcarbamate Basic information
Product Name:Ethyl 2-(4-phenoxyphenoxy)ethylcarbamate
Synonyms:Ethyl 2-[p-phenoxy] ethyl carbamate;Carbamic acid, 2-(4-phenoxyphenoxy)ethyl-, ethyl ester;fenoxycarb (ansi,bsi,iso);FENOXYXARB;Ethyl 2-(4-phenoxyphenoxy)ethylcarbamate;Fenoxycarb;ethyl [2-(4-phenoxyphenoxy)ethyl]carbamate fenoxycarb;2-(4-Phenoxyphenoxy)ethylcarbamic acid ethyl ester
CAS:72490-01-8
MF:C17H19NO4
MW:301.34
EINECS:276-696-7
Product Categories:INSECTICIDE
Mol File:72490-01-8.mol
Ethyl 2-(4-phenoxyphenoxy)ethylcarbamate Structure
Ethyl 2-(4-phenoxyphenoxy)ethylcarbamate Chemical Properties
Melting point 53-54°
Boiling point 442.47°C (rough estimate)
density 1.1222 (rough estimate)
vapor pressure 0Pa at 25℃
refractive index 1.5400 (estimate)
Fp 224 °C
storage temp. Store at -20°C
solubility 4.6g/L in organic solvents at 20 ℃
form neat
pka12.13±0.46(Predicted)
Water Solubility 7.9mg/L at 25℃
BRN 6932817
LogP4.07 at 25℃
EPA Substance Registry SystemFenoxycarb (72490-01-8)
Safety Information
Hazard Codes N
Risk Statements 50/53
Safety Statements 60-61
RIDADR UN 3077 9 / PGIII
WGK Germany 3
RTECS FD0423000
Hazardous Substances Data72490-01-8(Hazardous Substances Data)
ToxicityLD50 in rats (mg/kg): 9220 i.p.; 16800 orally (Dorn)
MSDS Information
Ethyl 2-(4-phenoxyphenoxy)ethylcarbamate Usage And Synthesis
DescriptionFenoxycarb is a non-neurotoxic carbamate insecticide that acts as an insect growth regulator via juvenile hormone-like activity. It inhibits terminal development of first instar and newly transformed second instar nymphs of Florida red scale (C. aonidum) when used at a concentration of 0.0125% AI. Fenoxycarb (5 and 10 mg AI/colony) reduces the colony size index of laboratory colonies of red imported fire ants (S. invicta) by 93.6 to 95.9% at 8 weeks post-treatment. It is toxic to D. magna (LC50 = 0.5 mg a.s./L) and fish including O. mykiss, L. macrochirus, C. carpio, I. punctatus, and C. variegatus (LC50s = 0.66-1.5 mg a.s./L), but is not toxic to rats (LD50 = >10,000 mg/kg). Fenoxycarb is also an antagonist of α4β40-, α4β2-, α3β4-, and α3β2-containing rat nicotinic acetylcholine receptors (nAChRs; IC50s = 3, 2.4, 1.8, and 7.6 μM, respectively) but not rat brain acetylcholinesterase (AChE; IC50 = >1,000 μM).
Chemical PropertiesColorless crystalline
UsesInsecticide.
UsesFenoxycarb is a carbamate insect growth regulator by preventing immature insects from reaching maturity by mimicking juvenile hormone.
DefinitionChEBI: Fenoxycarb is a carbamate ester that is the O-ethyl carbamate of 2-(4-phenoxyphenoxy)ethylamine. It has a role as a juvenile hormone mimic, an environmental contaminant, a xenobiotic and an insecticide. It is an aromatic ether and a carbamate ester. It is functionally related to a 4-phenoxyphenol.
General DescriptionWhite crystalline solid. Selective insecticide.
Air & Water ReactionsSlightly water soluble.
Reactivity ProfileEthyl 2-(4-phenoxyphenoxy)ethylcarbamate is a carbamate ester. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates.
Flammability and ExplosibilityNotclassified
Agricultural UsesInsecticide, Miticide: Fenoxycarb is an insect growth regulator, sex attractant, or feeding stimulant. It is intended to be used to inhibit metamorphosis of juvenile insects to the adult stage. It is used as bait to control a broad spectrum of insects on olives, vines, fruit, cotton, and stored products. It is used to control fire ants, cockroaches, mosquitos, beetles, moths, scale and sucking insects.
Trade nameAWARD; ABG 6215; ACR®-2984 F; ACR® 2913; BASUS®[C]; COMPLY®; ECTOGARD®[C]; ELIMINATOR®[C]; INSEGAR®; LogIC®; LUFOX®; PICTYL®; PRECISION®; TORUS®[C]; RO 13-5223®; VARIKILL®
Ethyl 2-(4-phenoxyphenoxy)ethylcarbamate Preparation Products And Raw materials
ETHIOFENCARB BENDIOCARB Molosultap Mercaptodimethur Propoxur MPMC Carbosulfan Cartap hydrochloride BENFURACARB ALANYCARB FENOXYCARB 25% WG FENOXYCARB SOLUTION 100UG/ML IN TOLUENE 1ML FENOXYCARB PESTANAL, 250 MG Fenoxycarb E.C. Fenoxycarb Urethane Fenoxycarb W.P. FENOXYCARB SOLUTION 100UG/ML IN ACETONITRILE 1ML

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