ChemicalBook Product Catalog Chemical Reagents Organic reagents Sulfone, sulfoxide compound METHYLSULFONYLACETONE

METHYLSULFONYLACETONE

METHYLSULFONYLACETONE Basic information
Product Name:METHYLSULFONYLACETONE
Synonyms:1-METHANESULPHONYLPROPAN-2-ONE;Methylsulfonylacetone, 98+%;Methanesulfonylacetone, 98+%;METHYLSULFONYLACETONE;METHANESULFONYLACETONE;METHANESULPHONYLACETONE;Methylsulphonylacetone;1-(methylsulphonyl)acetone
CAS:5000-46-4
MF:C4H8O3S
MW:136.17
EINECS:225-665-6
Product Categories:Organic Building Blocks;Sulfones;Sulfur Compounds
Mol File:5000-46-4.mol
METHYLSULFONYLACETONE Structure
METHYLSULFONYLACETONE Chemical Properties
Melting point 48-52 °C (lit.)
Boiling point 300.8±25.0 °C(Predicted)
density 1.208±0.06 g/cm3(Predicted)
Fp >230 °F
storage temp. 2-8°C
form powder or crystals
Water Solubility Insoluble in water.
BRN 1754113
CAS DataBase Reference5000-46-4(CAS DataBase Reference)
Safety Information
Safety Statements 22-24/25
WGK Germany 3
HS Code 29302000
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
METHYLSULFONYLACETONE Usage And Synthesis
UsesMethylsulfonylacetone is used as reactant for Stereoselective preparation of chiral cyclic ketones. It is used in the Preparation of poly-substituted pyridines. It aids for Gold-catalyzed Friedlander cyclocondensation reaction. It is used as reactant in Radical homoallylation reactions, multicomponent cyclocondensation with aldehydes and aminoazoles.
General DescriptionMethanesulfonylacetone is a sulfonyl group-containing active methylene compound. It can react with Baylis–Hillman acetates in dimethylformamide/potassium carbonate system to form ortho-hydroxyacetophenone derivatives.
METHYLSULFONYLACETONE Preparation Products And Raw materials
Raw materialsmethylsulfinyloxymethane-->1-METHYLTHIO-2-PROPANONE-->Water-->Chloroacetone-->Sodium methanesulfinate-->BROMOACETONE-->Methanesulfonyl chloride-->Acetic acid
1-(4-TOLUENESULPHONYL)-3,3-DIMETHYLBUTANE-2-ONE 2-(PHENYLSULFONYL)ACETOPHENONE 4'-METHYL-2(P-TOLYL SULFONYL)ACETOPHENONE 1-(4-METHOXYPHENYL)-2-(PHENYLSULFONYL)-1-ETHANONE 2-(P-TOLUENESULFONYL)ACETOPHENONE 1-Hydroxyimino-3-methylsulfonylacetone 3-Chloro-1-phenylsulfonyl-2-propanone 1-(4'-CHLOROBENZENESULFONYL)-3,3-DIMETHYLBUTANE-2-ONE 1-(4-BROMOPHENYL)-2-((4-METHYLPHENYL)SULFONYL)ETHAN-1-ONE 2-PROPANONE, 1-[(4-METHOXYPHENYL)SULFONYL]- 2,5-DIPHENYL-4-HYDROXY-3-OXO-2,3-DIHYDROTHIOPHENE 1,1-DIOXIDE 4-TOLUENESULFONYLACETONE 3-((4-CHLOROPHENYL)SULFONYL)-4-ETHOXYBUT-3-EN-2-ONE 1-(4-CHLOROPHENYL)-2-[(4-CHLOROPHENYL)SULFONYL]-1-ETHANONE BENZENESULFONYLACETONE 1-(4-CHLORO-3-METHYLPHENYL)-2-((4-METHYLPHENYL)SULFONYL)ETHAN-1-ONE 2-METHYLSULFONYLACETOPHENONE 3-CHLORO-1-((4-METHYLPHENYL)SULFONYL)ACETONE
Email:[email protected] [email protected]
Copyright © 2024 Mywellwork.com All rights reserved.