Hydridotetrakis(triphenylphosphine)rhodium(I)

Hydridotetrakis(triphenylphosphine)rhodium(I) Basic information
Reaction
Product Name:Hydridotetrakis(triphenylphosphine)rhodium(I)
Synonyms:Hydridotetrakis(triphenylphosphine)rhodium(I), Rh 8.9% min;Hydridotetrakis(triphenylphosphine)rhodium(I) dec. 145-147C;Hydrido tetra(triphenylphosphine)rhodium;HYDRIDOTETRAKIS (TRIPHENYLPHOSPHINE) RHODATE (I);HYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RHODIUM(I);Hydridotetrakis(trip;Tetrakis(triphenylphosphine)rhodium(I) Hydride;HRh(PPh3)4
CAS:18284-36-1
MF:C72H61P4Rh+
MW:1153.06
EINECS:
Product Categories:chemical reaction,pharm,electronic,materials;Rh;Catalysis and Inorganic Chemistry;Chemical Synthesis;Rhodium
Mol File:18284-36-1.mol
Hydridotetrakis(triphenylphosphine)rhodium(I) Structure
Hydridotetrakis(triphenylphosphine)rhodium(I) Chemical Properties
Melting point 140-146 °C(lit.)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Soluble in chloroform, toluene
form Crystalline Powder
color Ochre
Sensitive Air Sensitive
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
TSCA No
HS Code 28439090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Hydridotetrakis(triphenylphosphine)rhodium(I) Usage And Synthesis
ReactionStarting material for the preparation of a rhodium/phosphine complex used in the synthesis of diarylsulfides from aryl fluorides and sulfur/organopolysulfides. Reactions of 18284-36-1
Chemical Propertiesyellow powder
UsesHydridotetrakis(triphenylphosphine)rhodium(I) is an inorganic compound that is used as a catalyst in various reactions.
Hydridotetrakis(triphenylphosphine)rhodium(I) Preparation Products And Raw materials
Dipotassium hexachloroiridate Ruthenium tetroxide Tris(triphenylphosphine)rhodiu Rhodium triiodide Carbonyltris(triphenylphosphine)rhodium(I) hydride Chloroiridic acid HYDROXY[(S)-BINAP]RHODIUM(I) DIMER Sodium hydride Hydridotetrakis(triphenylphosphine)rhodium(I) TRIPHENYLPHOSPHINE Sodium borohydride 1,2,3,4-Tetrahydronaphthalene Tetrakis(triphenylphosphine)palladium Sodium hydrosulfide Phosphine Triphenylphosphine Rhodium Hydrocortisone

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