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Methyl 4-bromo-3-methylbenzoate

Methyl 4-bromo-3-methylbenzoate Basic information
Product Name:Methyl 4-bromo-3-methylbenzoate
Synonyms:METHYL 4-BROMO-3-METHYLBENZOATE;METHYL 4-BROMO-M-TOLUATE;Methyl 4-bromo-3-met;2-Bromo-5-(methoxycarbonyl)toluene;4-Bromo-m-toluic Acid Methyl Ester 4-Bromo-3-methylbenzoic Acid Methyl Ester Methyl 4-Bromo-m-toluate;2-Bromo-5-(methoxycarbonyl)toluene, Methyl 4-bromo-m-toluate;Methyl 4-Bromo-3-Methoxynicotinate;Methyl 4-broMo-3-Methylbenzoate, 97%, 97%
CAS:148547-19-7
MF:C9H9BrO2
MW:229.07
EINECS:629-103-4
Product Categories:blocks;Bromides;Carboxes;Aromatic Esters;Benzene series;Benzoic acid;Acids & Esters;Bromine Compounds;C8 to C9;Carbonyl Compounds;Esters;Pyridines;bc0001
Mol File:148547-19-7.mol
Methyl 4-bromo-3-methylbenzoate Structure
Methyl 4-bromo-3-methylbenzoate Chemical Properties
Melting point 38-44 °C (lit.)
Boiling point 287.4±20.0 °C(Predicted)
density 1.433±0.06 g/cm3(Predicted)
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
solubility Methanol[soluble in]
solubility soluble in Methanol
form Low Melting Solid or Liquid
color White to yellow
BRN 6593534
CAS DataBase Reference148547-19-7(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
Hazard Note Irritant
HS Code 29163990
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Methyl 4-bromo-3-methylbenzoate Usage And Synthesis
Chemical PropertiesColorless low melting solid
UsesMethyl 4-bromo-3-methylbenzoate may be used in the preparation of:
  • 4-bromo-3-vinylbenzoic acid
  • 4-bromo-3-(methylphenyl)methanol
  • methyl (E)-4-bromo-3-[(phenylmethoxyimino)methyl]benzoate

It may be used as a starting material in the total synthesis of (-)-martinellic acid.
General DescriptionMethyl 4-bromo-3-methylbenzoate, an aromatic ester, undergoes Suzuki coupling with 2-chloroboronic acid to afford the corresponding biaryl.
Methyl 4-bromo-3-methylbenzoate Preparation Products And Raw materials
Raw materials4-Bromo-3-methylbenzoic acid-->Methyl 4-amino-3-methylbenzoate-->Methanol-->2,4-Dimethylbromobenzene-->Iodomethane
METHYL 2-BROMO-3-METHYLBENZOATE Methyl 4-amino-3-methylbenzoate Methyl 2-methyl-3-nitrobenzoate methyl 5-bromo-2-methyl-benzoate METHYL 3-BROMO-4-METHYLBENZOATE SPECS AE-562/12222711 4-BROMO-3,5-DIMETHYL-BENZOIC ACID METHYL ESTER Methyl Methyl 2-bromo-6-methylbenzoate METHYL 4-BROMO-2-METHYLBENZOATE TERT-BUTYL 4-BROMO-3-METHYLBENZOATE BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER METHYL 2-BROMO-4-METHYLBENZOATE Methyl 5-bromo-2-methylbenzoate Methyl 4-Bromo-3-(Trifluoromethyl)benzoate ETHYL 4-BROMO-3-METHYLBENZOATE METHYL 3-BROMO-2-METHYLBENZOATE bromo-Dragonfly
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