4-Fluoronitrobenzene

4-Fluoronitrobenzene Basic information
Uses
Product Name:4-Fluoronitrobenzene
Synonyms:4-Fluornitrobenzol;4-fluoro-1-nitrobenzene;Benzene,1-fluoro-4-nitro-;For fluoronitrobenzene;NSC 10281;p-fluoronitrobenzene anion;Fluoronitrobenzene3;Fluoronitrobenzenecolorlesssolid
CAS:350-46-9
MF:C6H4FNO2
MW:141.1
EINECS:206-502-8
Product Categories:Phenyls & Phenyl-Het;Nitro Compounds;Aromatic Halides (substituted);Halides;Nitrogen Compounds;Organic Building Blocks;Phenyls & Phenyl-Het
Mol File:350-46-9.mol
4-Fluoronitrobenzene Structure
4-Fluoronitrobenzene Chemical Properties
Melting point 21 °C (lit.)
Boiling point 205 °C (lit.)
density 1.33 g/mL at 25 °C (lit.)
vapor density >1 (vs air)
vapor pressure 5.5 mm Hg ( 70 °C)
refractive index n20/D 1.531(lit.)
Fp 182 °F
storage temp. Sealed in dry,Room Temperature
solubility Chloroform (Slightly), Methanol (Slightly)
form Liquid After Melting
color deep greenish-yellow
Specific Gravity1.330
Water Solubility Insoluble in water.
BRN 606923
Stability:Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKeyWFQDTOYDVUWQMS-UHFFFAOYSA-N
LogP1.8 at 20℃
CAS DataBase Reference350-46-9(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, 1-fluoro-4-nitro-(350-46-9)
EPA Substance Registry Systemp-Fluoronitrobenzene (350-46-9)
Safety Information
Hazard Codes Xn,T,Xi
Risk Statements 20/21/22-33
Safety Statements 36-36/37
RIDADR UN 2811 6.1/PG 3
WGK Germany 1
RTECS DA1400000
Hazard Note Toxic/Irritant
TSCA Yes
HazardClass 6.1
PackingGroup III
HS Code 29049085
Hazardous Substances Data350-46-9(Hazardous Substances Data)
MSDS Information
ProviderLanguage
p-Fluoronitrobenzene English
ACROS English
SigmaAldrich English
ALFA English
4-Fluoronitrobenzene Usage And Synthesis
Uses4-Nitrofluorobenzene, is an aryl fluorinated building block, and a common intermediate used for the synthesis of many industrial useful compounds. It is used for the preparation of novel soluble aromatic polyimides, such as 1,3,5-Tris(4-aminophenoxy)benzene (TAB).
Chemical Propertiesyellow liquid
Uses1-Fluoro-4-nitrobenzene used as a component of hair dyes, as pharmaceutical intermediates. It is also used for the preparation of novel soluble aromatic polyimides
Synthesis Reference(s)Journal of the American Chemical Society, 78, p. 6034, 1956 DOI: 10.1021/ja01604a022
Tetrahedron, 52, p. 23, 1996 DOI: 10.1016/0040-4020(95)00867-8
Tetrahedron Letters, 30, p. 7199, 1989 DOI: 10.1016/S0040-4039(01)93933-4
Flammability and ExplosibilityNonflammable
Purification MethodsCrystallise it from EtOH. [Beilstein 5 H 241, 5 IV 719.]
Fluorine 4-Fluoronitrobenzene 2,4-Dichloro-5-fluoronitrobenzene FLUORONITROBENZENE 1,1,2TRIFLUORONITROBENZENE p-Nitrobenzoic acid 3-(4-Nitrophenyl)-beta-alanine ρ-Nitrobenzenesulphonic acid 4-Nitrophenyl phosphate bis(cyclohexylammonium) salt 4-Bromo-1-fluoro-2-nitrobenzene 1,2,3-Trifluoro-4-nitrobenzene 3,4-Difluoronitrobenzene Nitrobenzene 4-Nitrobenzaldehyde 2,6-Difluoronitrobenzene 1-Fluoro-2-nitrobenzene 3-Chloro-4-fluoronitrobenzene 1,3-Dinitrobenzene

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