BIS(DIETHYLAMINO)PHENYLPHOSPHINE 97

BIS(DIETHYLAMINO)PHENYLPHOSPHINE 97 Basic information
Product Name:BIS(DIETHYLAMINO)PHENYLPHOSPHINE 97
Synonyms:BIS(DIETHYLAMINO)PHENYLPHOSPHINE 97;N,N,N′N′-Tetraethylphenylphosphonous diamide;NSC 244337;Phenylphosphonous tetraethyldiamide;Bis(diethylamino)phenylphosphine 97%;Phosphonous diamide, N,N,N',N'-tetraethyl-P-phenyl-
CAS:1636-14-2
MF:C14H25N2P
MW:252.34
EINECS:
Product Categories:Catalysis and Inorganic Chemistry;Phosphine Ligands;Phosphorus Compounds
Mol File:1636-14-2.mol
BIS(DIETHYLAMINO)PHENYLPHOSPHINE  97 Structure
BIS(DIETHYLAMINO)PHENYLPHOSPHINE 97 Chemical Properties
Boiling point 80 °C0.005 mm Hg(lit.)
density 0.971 g/mL at 25 °C(lit.)
Fp 223 °F
pka6.94±0.70(Predicted)
Safety Information
WGK Germany 3
MSDS Information
BIS(DIETHYLAMINO)PHENYLPHOSPHINE 97 Usage And Synthesis
UsesElectron-withdrawing cocatalyst in rhodium catalyzed hydroformylation reactions. Ligand precatalyst for Heck coupling reactions. Reactant for: Preparation of palladium chiral P-N ligand complexes for regio- and stereo-selective dimerization reactions. Preparation of palladium tautomeric ferrocenylphosphinites as catalysts for Suzuki-Miyaura coupling. Trimethylsilyl halide-promoted Michaelis-Arbuzov rearrangement of phosphinites and phosphites.
Uses
  • Electron-withdrawing cocatalyst in rhodium catalyzed hydroformylation reactions
  • Ligand precatalyst for Heck coupling reactions

Reactant for:
  • Preparation of palladium chiral P-N ligand complexes for regio- and stereo-selective dimerization reactions
  • Preparation of palladium tautomeric ferrocenylphosphinites as catalysts for Suzuki-Miyaura coupling
  • Trimethylsilyl halide-promoted Michaelis-Arbuzov rearrangement of phosphinites and phosphites
BIS(DIETHYLAMINO)PHENYLPHOSPHINE 97 Preparation Products And Raw materials

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