(R)-(+)-1-(4-Methoxyphenyl)ethylamine

(R)-(+)-1-(4-Methoxyphenyl)ethylamine Basic information
Product Name:(R)-(+)-1-(4-Methoxyphenyl)ethylamine
Synonyms:(R)-p-Methoxyphenylethylamine;Benzenemethanamine, 4-methoxy-.alpha.-methyl-, (.alpha.R)-;(1R)-1-(4-Methoxyphenyl)ethylamine;(R)-(+)-4-Methoxy-alpha-MethylbenzylaMine ChiPros(R), produced by BASF, 99%;R - the Methoxy phenethylaMine;(R)-(+)-4-Methoxy-;(R)-(+)-1-(4-Methoxyphenyl)ethylamine, 99%, ee 99+%;(R)-(+)-4-METHOXY-ALPHA-METHYLBENZYLAMIN
CAS:22038-86-4
MF:C9H13NO
MW:151.21
EINECS:606-907-3
Product Categories:API intermediates;Amines (Chiral);Chiral Building Blocks;Synthetic Organic Chemistry;Amines and Derivatives;CHIRAL CHEMICALS
Mol File:22038-86-4.mol
(R)-(+)-1-(4-Methoxyphenyl)ethylamine Structure
(R)-(+)-1-(4-Methoxyphenyl)ethylamine Chemical Properties
Melting point <-20°C
alpha 32 º (neat)
Boiling point 65°C 0,4mm
density 1.024 g/mL at 20 °C(lit.)
refractive index n20/D 1.533
Fp 65°C/0.38mm
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
pka9.29±0.10(Predicted)
Water Solubility Soluble in water (10g/L).
Sensitive Air Sensitive
BRN 2413029
InChIKeyJTDGKQNNPKXKII-SSDOTTSWSA-N
CAS DataBase Reference22038-86-4(CAS DataBase Reference)
Safety Information
Hazard Codes C
Risk Statements 34-22
Safety Statements 26-36/37/39-45
RIDADR UN 2735 8/PG 3
WGK Germany 3
10-34
HazardClass 8
PackingGroup III
HS Code 29222990
MSDS Information
(R)-(+)-1-(4-Methoxyphenyl)ethylamine Usage And Synthesis
Chemical PropertiesColorless liquid
Uses(R)-(+)-4-Methoxy-α-methylbenzylamine can be used as a reactant to prepare:
  • Enantiopure stereoisomers of hemicryptophanes, which are used for the recognition of glucopyranosides.
  • Bicyclic Geissman-Waiss lactone via intramolecular ring-closure reaction of the diastereomeric mixture of sulfonium salts.
  • N-[(1R)-1-(4-Methoxyphenyl)ethyl]-N′-methylthiourea by reacting with methyl isothiocyanate.

Uses(R)-(+)-1-(4-Methoxyphenyl)ethylamine use in diastereo-and enantioselective Michael addition reactions. Thiazoles has been prepared from (R)-(+)-1-(4-Methoxyphenyl)ethylamine.
(R)-(+)-1-(4-Methoxyphenyl)ethylamine Preparation Products And Raw materials
4-Methoxybenzyl cyanide 2-(4-Benzyloxy-3-methoxyphenyl)ethylamine Hydrochloride,-(4-Benzyloxy-3-methoxyphenyl)ethylamine Hydrochloride 4-IODO-2,5-DIMETHOXYPHENETHYLAMINE Methoxy N-Methyl-2-(4-methoxyphenyl)ethylamine 3,4-Dimethoxyphenethylamine 2,5-Dimethoxyphenethylamine hydrochloride D/L-AMPHETAMINE HYDROCHLORIDE m-Anisyl alcohol 4-Hydroxybenzylamine 1-(3'-FLUORO-4'-METHOXYPHENYL)ETHYLAMINE L-1-Phenylethylamine 2-(2-CHLORO-3,4-DIMETHOXYPHENYL) ETHYLAMINE (1S)-(4-Fluoro-3-methoxyphenyl)ethylamine N-(2-chlorophenylpropyl)-1-(3-methoxyphenyl)ethylamine N-Methyl-N-(3-chloropropyl)-3,4-dimethoxyphenethylamine 4-BROMO-2-METHOXYBENZYLAMINE 3-ETHOXY-4-METHOXYPHENETHYLAMINE

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