Dibutyl phosphate

Dibutyl phosphate Basic information
Product Name:Dibutyl phosphate
Synonyms:di-n-butylhydrogenphosphate;dp4(couplingagent);hdbp;phosphatededibutyle;di-n-butylphosphoric acid;Phosphorsuredi-n-butylester;DIBUTYL PHOSPHATE (DBP);Di-n-butyl phosphate, 97+%
CAS:107-66-4
MF:C8H19O4P
MW:210.21
EINECS:203-509-8
Product Categories:
Mol File:107-66-4.mol
Dibutyl phosphate Structure
Dibutyl phosphate Chemical Properties
Melting point -13 °C
Boiling point 250 °C
density 1.06 g/mL at 20 °C (lit.)
vapor pressure 0Pa at 20℃
refractive index n20/D 1.428
Fp 188 °C
storage temp. Store below +30°C.
solubility Chloroform (Soluble), Methanol (Slightly)
pka1.53±0.50(Predicted)
form Liquid
Specific Gravity1.1
color Clear
Water Solubility insoluble
BRN 607224
Exposure limitsACGIH: TWA 5 mg/m3 (Skin)
OSHA: TWA 1 ppm(5 mg/m3)
NIOSH: IDLH 30 ppm; TWA 1 ppm(5 mg/m3); STEL 2 ppm(10 mg/m3)
InChIKeyJYFHYPJRHGVZDY-UHFFFAOYSA-N
LogP-0.9 at 25℃
CAS DataBase Reference107-66-4(CAS DataBase Reference)
EPA Substance Registry SystemDibutyl phosphate (107-66-4)
Safety Information
Hazard Codes Xi,C
Risk Statements 37/38-41-38-34-40
Safety Statements 26-39-45-36/37/39-25
RIDADR 3261
WGK Germany 1
RTECS TB9605000
TSCA Yes
HazardClass 8
PackingGroup III
HS Code 29199000
Hazardous Substances Data107-66-4(Hazardous Substances Data)
IDLA30 ppm
MSDS Information
ProviderLanguage
Dibutyl phosphate English
ACROS English
SigmaAldrich English
ALFA English
Dibutyl phosphate Usage And Synthesis
Chemical PropertiesDibutyl phosphate is a pale amber to brown, odorless liquid. It is used as a catalyst for cross-linking in the paint industry and antistatics for the textile industry. It is stable in neutral, acidic or alkaline solution, and is classified as "not readily biodegradable" but inhererently biodegradable.The half-life time of 4.99 years is estimated for the degradation of dibutyl phosphate in air by the reaction with photochemically produced OH radicals. (MITI, Japan).
UsesPale amber liquid
UsesDibutyl phosphate is used as a plasticizer for polymer system and hydraulic fluid directly and used as a catalyst for cross-linking in paint industry. It is used as an antifoam agent in ore separation process and as an antistatic agent in the textile industry. It can be used as a precursor for antistatics, as a mould release agent in polyurethane applications and, as a non volatile acidic catalyst soluble in organic media.
DefinitionChEBI: Dibutyl phosphate is a dialkyl phosphate.
General DescriptionPale-amber odorless liquid. Mp: -13°C, bp: 135-138°C. Density: 1.06 g cm-3. Moderately soluble in water (18 g / L at 20°C).
Reactivity ProfileDibutyl phosphate Is non-flammable, but combustible (flash point 188°C). Auto-ignition temperature is 420°C. Emits irritating or toxic fumes in a fire. Is a moderately strong acid obtained by the partial esterification of phosphoric acid. Reacts exothermically and vigorously with bases. Incompatible with strong oxidizing agents, alkali metals, heat, or plastic. Reacts with many metals liberating flammable/explosive hydrogen gas.
Health HazardDibutyl phosphate is an irritant of the eyes and mucous membranes.
Flammability and ExplosibilityNonflammable
Safety ProfileModerately toxic by ingestion. When heated to decomposition it emits toxic fumes of POx. See also PHOSPHATES.
Potential ExposureThis material is used as a catalyst in organic synthesis.
ShippingUN1760 Corrosive liquids, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required. UN3261 Corrosive solid, acidic, organic, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required.
IncompatibilitiesDibutyl phosphate is a medium strong acid. Incompatible with oxidizers (chlorates, nitrates, per- oxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. Attacks many metals forming flammable and explosive hydrogen gas. Attacks some plas- tics, rubber, and coatings.
Dibutyl phosphate Preparation Products And Raw materials
Preparation ProductsMethyl Oleate
DICETYL PHOSPHATE DI(LAURYL) PHOSPHORIC ACID Calcium phosphate TRIHEXYL PHOSPHATE ROCK PHOSPHATE Tributyl phosphate Trisodium phosphate Tris(2-ethylhexyl) phosphate PHOSPHORIC ACID DI-N-DECYL ESTER PHOSPHORIC ACID TRI-N-AMYL ESTER DI-N-OCTADECYL PHOSPHATE Diisobutyl phthalate phosphate trioctyl phosphate DIBUTYL CARBONATE diisoctyl acid phosphate DI-N-OCTYL PHENYL PHOSPHATE Dibutyl maleate

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