Aniline-2-sulfonic acid

Aniline-2-sulfonic acid Basic information
Product Name:Aniline-2-sulfonic acid
Synonyms:2-SULFOANILINE;2-AMINOBENZENESULFONIC ACID;ANILINE-2-SULFONIC ACID;ANILINE-O-SULFONIC ACID;2-aminobenzenesulphonic acid;ORTHO AMINO PHENOL SULPHONIC;ORTHANILIC ACID (2-AMINOBENZENESULFONIC ACID);Aniline-2-sulfonic acid, tech., 83%
CAS:88-21-1
MF:C6H7NO3S
MW:173.19
EINECS:201-810-9
Product Categories:Intermediates of Dyes and Pigments
Mol File:88-21-1.mol
Aniline-2-sulfonic acid Structure
Aniline-2-sulfonic acid Chemical Properties
Melting point 300 °C
Boiling point 363.26℃[at 101 325 Pa]
density 1.342 (estimate)
vapor pressure 0Pa at 25℃
refractive index 1.5500 (estimate)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility 3.565g/L in organic solvents at 20 ℃
form Crystalline Powder
pka2.48(at 25℃)
color White to beige
Water Solubility sparingly soluble
Merck 14,6882
BRN 1309204
InChIKeyZMCHBSMFKQYNKA-UHFFFAOYSA-N
LogP0 at 23℃
CAS DataBase Reference88-21-1(CAS DataBase Reference)
NIST Chemistry ReferenceAniline-o-sulfonic acid(88-21-1)
EPA Substance Registry Systemo-Aminobenzenesulfonic acid (88-21-1)
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 26-36/37/39-45-28A
RIDADR UN 2585 8/PG 3
WGK Germany 3
RTECS DB4727700
TSCA Yes
HazardClass 8
PackingGroup III
HS Code 29214200
MSDS Information
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Aniline-2-sulfonic acid English
SigmaAldrich English
ACROS English
Aniline-2-sulfonic acid Usage And Synthesis
Chemical PropertiesLIGHT BROWN FINE CRYSTALLINE POWDER
DefinitionChEBI: An aminobenzenesulfonic acid carrying an amino group at position 2.
General DescriptionLight brown powder.
Air & Water ReactionsSoluble in water.
Reactivity ProfileAniline-2-sulfonic acid is an amino acid. Reacts weakly with both acids and bases.
Fire HazardFlash point data for Aniline-2-sulfonic acid are not available, however Aniline-2-sulfonic acid is probably combustible.
Flammability and ExplosibilityNonflammable
Purification MethodsCrystallise orthanilic acis from aqueous solution, containing 20mL of conc HCl per L, then crystallise it from distilled water, and dry it in a vacuum desiccator over Sicapent (m 315o). When an aqueous solution is chilled below 13.5o, the hydrated form of the acid is obtained. It is used for the determination of nitrite and nitrate. The S-benzylisothiuronium salt has m 137o (from H2O). [Wertheim Org Synth Coll Vol II 471 1943, Beilstein 14 H 681, 14 I 714, 14 II 429, 14 III 1896, 14 IV 2638.]
ACID YELLOW 40 ACID ORANGE 63 REACTIVE BLUE 4 2,4-Diaminobenzenesulfonic acid ACID FUCHSIN CALCIUM SALT ACID VIOLET 34 ACID RED 66 ACID BLUE 41 REACTIVE BLACK 5 Ascoric Acid Acid Green 25 4-Amino-benzenesulfonic acid monosodium salt SULFONIC ACID phosphoric acid ACID BLUE 25 Sodium 2-aminosulphanilate ACID BLUE 40 ACID GREEN 27 (C.I. 61580)

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