4-(Methylthio)phenylboronic acid

4-(Methylthio)phenylboronic acid Basic information
Product Name:4-(Methylthio)phenylboronic acid
Synonyms:4-(Methylsulfanyl)phenylboronic acid, 95%, May contain varying aMounts of anhydride;Boronic acid, B-[4-(methylthio)phenyl]-;THIOANISOLE-4-BORONIC ACID;RARECHEM AH PB 0130;P-(METHYLTHIO)PHENYLBORONIC ACID;4-(Methylthio)phenylboronic acid 4-Thioanisoleboronic acid;4-(Methylthiophenyl)boronicacid,min.97%;4-Methylthiopenylboronic Acid
CAS:98546-51-1
MF:C7H9BO2S
MW:168.02
EINECS:
Product Categories:Organoborons;Boronic acids;Organometallic Reagents;Boronate Ester;Potassium Trifluoroborate;Aryl Boronic Acids;Boronic Acids and Derivatives;Chemical Synthesis;Monosubstituted Aryl Boronic Acids;B (Classes of Boron Compounds);organic or inorganic borate;Boronic Acid;Azoles;blocks;BoronicAcids;Boric Acid;Aryl
Mol File:98546-51-1.mol
4-(Methylthio)phenylboronic acid Structure
4-(Methylthio)phenylboronic acid Chemical Properties
Melting point 210-214 °C (lit.)
Boiling point 333.5±44.0 °C(Predicted)
density 1.22±0.1 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility soluble in Methanol
pka8.56±0.10(Predicted)
form Crystalline Powder
color Off-white
BRN 3247219
CAS DataBase Reference98546-51-1(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 37/39-26-36-7/9
WGK Germany 3
TSCA No
HazardClass IRRITANT
HS Code 29163990
MSDS Information
ProviderLanguage
4-Thioanisoleboronic acid English
SigmaAldrich English
ACROS English
ALFA English
4-(Methylthio)phenylboronic acid Usage And Synthesis
Chemical PropertiesOff-white crystalline powder
UsesReactant involved in:
  • Suzuki-Miyaura cross coupling reactions with 2-aryl-1-bromo-1-nitroethenes or alkynyl bromides
  • Addition reactions with naphthyridine N-oxides
  • Oxyarylation of Heck reaction intermediates for synthesis of THF derivatives
  • Sulfoxidation reactions
  • Copper-catalyzed halogenation
4-Aminophenylboronic acid 4-Tolylboronic acid 4-(TERT-BUTYLSULFANYL)PHENYLBORONIC ACID 4-(Methylthio)phenylboronic acid IFLAB-BB F2108-0004 4-(ISOPROPYLSULFONYLPHENYL)BORONIC ACID 4-(ETHYLSULFONYL)PHENYLBORONIC ACID THIANTHRENE-2-BORONIC ACID 4-(TETRAHYDRO-2H-PYRAN-2-YLSULFANYL)PHENYLBORONIC ACID 4-ETHYLSULFINYLPHENYLBORONIC ACID 4-(METHYLTHIO)PHENYLBORONIC ACID PINACOLATE 4-PROPYLSULFANYLPHENYLBORONIC ACID 4-BENZYLTHIOPHENYLBORONIC ACID PHENYLMERCURIC BORATE 4-(METHOXYMETHYLTHIO)PHENYLBORONIC ACID 4-ISOPROPYLTHIOPHENYLBORONIC ACID 4-(Methanesulfonyl)phenylboronic acid pinacol ester AKOS BRN-0446

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