4-Vinylanilin

4-Vinylanilin Basic information
Product Name:4-Vinylanilin
Synonyms:4-Aminostyrene, 97%, stab. with 100ppm 4-t-butylcatechol;4-Vinylaniline, 90%,tech;1-(p-Aminophenyl)ethene;4-Ethenylaniline;Styrene-4-amine;4-Ethenylaniline, 4-Vinylaniline;4-Vinylaniline, 4-Ethenylaniline;4-Vinylaniline, tech., 90% 1GR
CAS:1520-21-4
MF:C8H9N
MW:119.16
EINECS:216-185-8
Product Categories:Fluorenes, etc. (reagent for high-performance polymer research);Reagent for High-Performance Polymer Research;Functional Materials;Styrenes
Mol File:1520-21-4.mol
4-Vinylanilin Structure
4-Vinylanilin Chemical Properties
Melting point 23 °C
Boiling point 213-214 °C(lit.)
density 1.017 g/mL at 25 °C(lit.)
refractive index n20/D 1.626(lit.)
Fp 210 °F
storage temp. 2-8°C
solubility Soluble in benzene, acetone and methanol.
form Liquid or Low Melting Solid
pka4.73±0.10(Predicted)
color Yellow to red
BRN 2204173
Stability:Stable, but 0.1% sodium hydroxide may be added to inhibit polymerisation. Incompatible with strong oxidizing agents.
InChIKeyLBSXSAXOLABXMF-UHFFFAOYSA-N
CAS DataBase Reference1520-21-4(CAS DataBase Reference)
EPA Substance Registry System4-Vinylaniline (1520-21-4)
Safety Information
Hazard Codes Xn,T,Xi
Risk Statements 36/37/38-48/20/21/22-43-40-33-20/21/22
Safety Statements 26-36/37-36
RIDADR 2811
WGK Germany 3
Hazard Note Toxic
TSCA Yes
HazardClass KEEP COLD
PackingGroup III
HS Code 29214990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
4-Vinylanilin Usage And Synthesis
Chemical Propertiesliquid
Uses4-Aminostyrene undergoes graft copolymerization with poly(tetrafluoroethylene) (PTFE)1 and Si surface,2 followed by oxidative copolymerization with aniline. Thus, it renders PTFE and Si surface conductive.1 4-VAn is coupled with hydrogen terminated Si surfaces for electroless metal and synthetic metal deposition.3 Palladium(II) schiff base complexes derived from Allylamine and vinylaniline has been reported.4 It also acts as a second surfactant for coating nanomagnetic particles.5 It is used in functionalization of single-walled carbon nanotube through solvent free functionalization.
DefinitionChEBI: 4-Vinylaniline is a member of styrenes.
Synthesis Reference(s)The Journal of Organic Chemistry, 53, p. 918, 1988 DOI: 10.1021/jo00239a056
General Description4-Vinylaniline (4-VAn) is a primary amine surfactant.
4-Vinylanilin Preparation Products And Raw materials
Preparation ProductsMETHYL 4-(4-AMINOPHENYL)BUTANOATE-->N-Methyl-4-vinylaniline-->P-VINYLPHENYL ISOTHIOCYANATE-->(E)-4-(3, 5-Dimethoxystyryl) aniline
4-Nitrocinnamic acid 2-AMINOSTYRENE 4-(Dimethylamino)cinnamaldehyde ACID FUCHSIN CALCIUM SALT Basic Red 9 2,5-DIMETHOXY-4'-NITROSTILBENE 3-AMINOSTYRENE,M-AMINOSTYRENE,3-Aminostyrene, (Stabilized with KOH) POLY(4-AMINOSTYRENE) Coumarin 151 RHODAMINE 6G TETRAFLUOROBORATE DACM styrene-4-aminostyrene copolymer 7-Dimethylamino-4-methylcoumarin SITS TRANS-4-DIMETHYLAMINOCINNAMONITRILE Pigment Violet 3 Coumarin 120 Coumarin 2

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