Allyl-α-ionone

Allyl-α-ionone Basic information
Product Name:Allyl-α-ionone
Synonyms:1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-1,6-heptadien-3-one;1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-6-heptadien-3-one;6-Heptadien-3-one,1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-1;allylalpha-ionon;1-(2,6,6-TRIMETHYLCYCLOHEX-2-ENYL)HEPTA-1,6-DIEN-3-ONE;1-(2,6,6-trimethyl-2-cyclohexen-1-yl)hepta-1,6-dien-3-one;ALLYL ALPHA-IONONE 65+%;1,6-Heptadien-3-one, 1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-
CAS:79-78-7
MF:C16H24O
MW:232.36
EINECS:201-225-9
Product Categories:A-B;Alphabetical Listings;Flavors and Fragrances
Mol File:79-78-7.mol
Allyl-α-ionone Structure
Allyl-α-ionone Chemical Properties
Boiling point 102-104 °C0.2 mm Hg(lit.)
density 0.928 g/mL at 25 °C(lit.)
refractive index n20/D 1.505(lit.)
FEMA 2033 | ALLYL ALPHA-IONONE
Fp >230 °F
Odorat 10.00 % in dipropylene glycol. green floral woody orris tropical weedy waxy leather
Odor Typefruity
JECFA Number401
LogP5.13
CAS DataBase Reference79-78-7(CAS DataBase Reference)
EPA Substance Registry System1,6-Heptadien-3-one, 1-(2,6,6-trimethyl-2-cyclohexen-1-yl)- (79-78-7)
Safety Information
WGK Germany 2
RTECS MI5550000
MSDS Information
ProviderLanguage
SigmaAldrich English
Allyl-α-ionone Usage And Synthesis
Chemical PropertiesA yellow liquid with a meaty, spicy, slightly floral, woody taste and a strong fruital aroma reminiscent of pineapple
PreparationBy condensation of citral and allyl acetone in the presence of sodium methoxide and subsequent ring closure in the presence of boron trifluoride.
DefinitionChEBI: 1-(2,6,6-Trimethyl-2-cyclohexen-1-yl)-1,6-heptadien-3-one is a sesquiterpenoid.
Taste threshold valuesTaste characteristics at 2 ppm: floral, sweet, fruity, woody and orris-like nuance
Safety ProfileA skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS.
Allyl-α-ionone Preparation Products And Raw materials
Raw materialsCitral
Cedryl acetate Coumarin (E,E)-Farnesol Linalool β-Lonone Ethyl maltol (-)-PERILLALDEHYDE 6 METHYL 3 HEPTEN 2 ONE alpha-Ionone Allyl-α-ionone METHYLIONONE Ionone 1,6-Heptadiene

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