ChemicalBook Product Catalog Organic Chemistry Organometallic compounds Rare-Earth Metal EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE

EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE

EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE Basic information
Product Name:EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE
Synonyms:TFMC-EU;TRIS(TRIFLUOROMETHYLHYDROXYMETHYLENE-D-CAMPHORATO)EUROPIUM(III);TRIS(3-TRIFLUOROACETYL-D-CAMPHORATO)EUROPIUM(III);TRIS[3-(TRIFLUOROMETHYLHYDROXYMETHYLENE)-D-CAMPHORATO]EUROPIUM(III);TRIS[3-(TRIFLUOROMETHYLHYDROXYMETHYLENE)-D-CAMPHORATO], EUROPIUM(III) DERIVATIVE;GDCL3:6H2O;EU(FACAM)3;Tris[3-(trifluoromethylhydroxymethylene)-D-camphorato], europium(III) derivative,95%
CAS:34830-11-0
MF:C36H42EuF9O6
MW:893.68
EINECS:252-232-9
Product Categories:Chiral Shift ReagentsStable Isotopes;Asymmetric Synthesis;Chiral Resolution Reagents;NMR - Buffers and Reagents;NMR Solvents and Reagents
Mol File:34830-11-0.mol
EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE Structure
EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE Chemical Properties
Melting point 195-198 °C(lit.)
form solid
optical activity[α]20/D +165°, c = 1% in chloroform (solvent is ethanol free)
Water Solubility Soluble in chloroform. Insoluble in water.
Sensitive Moisture Sensitive
CAS DataBase Reference34830-11-0
EPA Substance Registry SystemEuropium, tris[1,7,7-trimethyl-3-(trifluoroacetyl-.kappa.O)bicyclo[2.2.1]heptan-2-onato-.kappa.O]- (34830-11-0)
Safety Information
Safety Statements 24/25
WGK Germany 3
F 3-10
TSCA Yes
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE Usage And Synthesis
Chemical Propertiesyellow to orange powder
UsesOptically active NMR shift reagent. Used with Ag(fod) for the enantiomeric resolution of sec-butylisothiouronium chloride. Also reactant involved in synthesis of europium acetyl camphorate phosphine oxide complexes and reactions with 1,10-N,N?-phenanthroline dioxide derivatives.
EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE Preparation Products And Raw materials
Raw materialsEthanol-->Sodium hydroxide-->Hydrochloric acid-->Diethyl ether-->Hexane-->Sodium hydride-->Pentane-->DME-->Ethyl trifluoroacetate-->D-CAMPHOR-->Europium(III) chloride hexahydrate
D-CAMPHOR Rucaparib Camsylate L(-)-10-Camphorsulfonyl chloride (1R)-(-)-10-Camphorsulfonic acid (1S)-(+)-Camphor-10-sulphonic acid (-)-(8,8-DICHLOROCAMPHORYLSULFONYL)OXAZIRIDINE (+)-10-CAMPHORSULFONIMINE (+/-)-EXO EXO-2 3-CAMPHANEDIOL DL-CAMPHORIC ANHYDRIDE EUROPIUM (III) 2,4-PENTANEDIONATE EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE 2-ETHYLIDENECYCLOHEXANONE DL-Camphor ALLYLCYCLOPENTANE Camphor METHYLENECYCLOPENTANE ETHYLIDENECYCLOPENTANE 2,4-DIMETHYLCYCLOPENTANONE
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