AMINOTRIPHENYLSILANE

AMINOTRIPHENYLSILANE Basic information
Product Name:AMINOTRIPHENYLSILANE
Synonyms:1,1,1-TRIPHENYLSILYLAMINE;AMINOTRIPHENYLSILANE;TPSA;TRIPHENYLSILYLAMINE;TRIPHENYLAMINOSILANE;Triphenylsilanamine;[amino-di(phenyl)silyl]benzene;[azanyl-di(phenyl)silyl]benzene
CAS:4215-80-9
MF:C18H17NSi
MW:275.42
EINECS:224-147-7
Product Categories:Building Blocks;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks;Protected Amines
Mol File:4215-80-9.mol
AMINOTRIPHENYLSILANE Structure
AMINOTRIPHENYLSILANE Chemical Properties
Melting point 60-62 °C(lit.)
Boiling point 187-200 °C(Press: 2 Torr)
density 1.10±0.1 g/cm3(Predicted)
storage temp. −20°C
solubility Chloroform (Slightly), Methanol (Slightly)
pka6.31±0.70(Predicted)
form Solid
color White to Off-White
Hydrolytic Sensitivity7: reacts slowly with moisture/water
Stability:Hygroscopic, Moisture Sensitive
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26
WGK Germany 3
10-21
TSCA No
HS Code 2931900090
MSDS Information
ProviderLanguage
SigmaAldrich English
AMINOTRIPHENYLSILANE Usage And Synthesis
UsesTriphenylsilylamine is used as a reagent to produce 2-Amino-3-hydroxy-indoles with potent in vivo antimalarial activity. Triphenylsilylamine is also used to modify Mo/HZSM-5 catalysts and is predicted to have effects on selectivity in the methane-to-benzene (MTB) reaction.
UsesTriphenylsilylamine may be used in the following studies:
  • Preparation of dimers of the type [Ti(μ-NR)(NMe2)2]2 (R = 1-adamantyl, (t)Bu, SiPh3).
  • Silylation during the pretreatment of fused silica capillary surface to achieve a homogeneous film.
  • Preparation of triphenylsilylsulfinylamine, via reaction with thionylchloride.
  • To investigate the molecular tuning effect of silanation treatment for HZSM-5 crystals.
  • Synthesis of 9-aminopyrido[3′,3′:4,5]pyrrolo[1,2-c]pyrimidine (9-aminosubstituted derivative).
General DescriptionTriphenylsilylamine is a silyl compound.
AMINOTRIPHENYLSILANE Preparation Products And Raw materials
TRI-N-PROPYLSILANE Triphenylsilyl chloride TRIHEXYLSILANE TRIPHENYLETHOXYSILANE TRIOCTYLSILANE TRI-N-PROPYLCHLOROSILANE TRI-N-HEXYLCHLOROSILANE Triphenoxyvinylsilane AMINOTRIPHENYLSILANE N-Methyl-N-(phenylmethyl)-1,1,1-triphenylsilanamine TRIPHENYLSILYLAZIDE Triphenylsilane Diphenylsilane

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