2,6-BIS(CHLOROMETHYL)PYRIDINE

2,6-BIS(CHLOROMETHYL)PYRIDINE Basic information
Product Name:2,6-BIS(CHLOROMETHYL)PYRIDINE
Synonyms:ALPHA,ALPHA'-DICHLORO-2,6-LUTIDINE;α,α'-dichloro-2,6-lutidine;2,6-BIS(CHLOROMETHYL)PYRIDINE 98+%;2,6-Bis(chloromethyl)pyridine 99%;2,6-Bis(chloromethyl)pyridine,α,α′-Dichloro-2,6-lutidine;2,6-Bis(chloromethyl)pyridine >;Pyridine, 2,6-bis(chloromethyl)-
CAS:3099-28-3
MF:C7H7Cl2N
MW:176.04
EINECS:
Product Categories:Pyridine
Mol File:3099-28-3.mol
2,6-BIS(CHLOROMETHYL)PYRIDINE Structure
2,6-BIS(CHLOROMETHYL)PYRIDINE Chemical Properties
Melting point 73-78 °C (lit.)
Boiling point 110 °C / 3mmHg
density 1.275±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka2.19±0.24(Predicted)
form powder to crystal
color White to Almost white
BRN 116355
CAS DataBase Reference3099-28-3(CAS DataBase Reference)
Safety Information
Hazard Codes Xn
Risk Statements 22-37/38-41
Safety Statements 26-36/37/39
RIDADR UN 3335
WGK Germany 3
HS Code 29333990
MSDS Information
ProviderLanguage
SigmaAldrich English
2,6-BIS(CHLOROMETHYL)PYRIDINE Usage And Synthesis
Chemical PropertiesWhite to light yellow crystal powder
Uses2,6-Bis(chloromethyl)pyridine may be used in the following studies:
  • Synthesis of a sensitive fluorescent chemosensor for Hg2+, composed of two aminonaphthalimide fluorophores and a receptor of 2,6-bis(aminomethyl)pyridine.
  • Preparation of carbene pincer ligands, required for the preparation of palladium pincer carbene complex.
  • Synthesis of 2-(di-tert-butylphosphinomethyl)-6-diethylaminomethyl)pyridine, PNN ligand.
General Description2,6-Bis(chloromethyl)pyridine is a heterocyclic building block for the synthesis of a variety of pyridine derivatives. It coordinates with metal ions through N-atom to form complexes. The conformational flexibility of the bromomethyl arms makes it an ideal choice for the generation of macrocycles. 2,6-bis(chloromethyl)pyridine crystals are monoclinic with space group P21/c. Its synthesis has been reported. The FT-IR and FT-Raman spectra of 2,6-bis(chloromethyl)pyridine (BCMP) have been recorded in the regions 4000-400cm-1 and 3500-100cm-1, respectively.
Picoxystrobin 2,6-Pyridinedicarboxylic acid chloride 2,6-BIS(CHLOROMETHYL)PYRIDINE 2,6-Dichloromethyl pyridine hydrochloride 2,6-Lutidine Pyridine, 2,6-bis(chloromethyl)-, 1-oxide (9CI) (4,4'-Bipyridine)-2,2',6,6'-tetracarbonyltetrachloride

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