2,2':6',2''-TERPYRIDINE

2,2':6',2''-TERPYRIDINE Basic information
Application in coordination chemistry
Product Name:2,2':6',2''-TERPYRIDINE
Synonyms:2,2':6',2''-Terpyridine,97%;2,2′:6′,2′′-Terpyridine ,98%;6',2'']Terpyridine;2,2',2" TERPYRIDINE (Tripyridine, Tripyridyl);´;2,2':6',2"-Terpyridine 98%;2,6-BIS(PYRIDIN-2-YL)PYRIDINE;TERPY
CAS:1148-79-4
MF:C15H11N3
MW:233.27
EINECS:214-559-5
Product Categories:Pyrimidines;Achiral Nitrogen;Py-N
Mol File:1148-79-4.mol
2,2':6',2''-TERPYRIDINE Structure
2,2':6',2''-TERPYRIDINE Chemical Properties
Melting point 90-93 °C
Boiling point 370 °C
density 1.1901 (rough estimate)
refractive index 1.5610 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility dioxane: 0.1 g/mL, clear
form Crystalline powder
pka4.60±0.10(Predicted)
color Cream to yellow to brown
Water Solubility 1.472g/L(24.99 ºC)
BRN 11199
InChIKeyDRGAZIDRYFYHIJ-UHFFFAOYSA-N
CAS DataBase Reference1148-79-4(CAS DataBase Reference)
EPA Substance Registry System2,2':6',2''-Terpyridine (1148-79-4)
Safety Information
Hazard Codes T+,T
Risk Statements 27/28-37/38-41
Safety Statements 26-28-36/37/39-45
RIDADR UN 2811 6.1/PG 1
WGK Germany 3
TSCA Yes
HazardClass 6.1
PackingGroup I
HS Code 29333990
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
2,2':6',2''-TERPYRIDINE Usage And Synthesis
Application in coordination chemistry

As an NNN-tridentate ligand, the 2,2′:6′,2″-terpyridine plays an important role in coordination chemistry. With three coordination sites and low LUMO, terpyridine and its derivatives are one of the typical Pincer ligand and/or non-innocent ligands in transition metal catalysis. Interesting catalytic reactivities have been obtained with these tpy-metal complexes targeting some challenging transformations, such as C–C bond formation and hydrofunctionalization. The 2,2':6':2''-terpyridine ligand has literally shaped the coordination chemistry of transition metal complexes in a plethora of fields.

DescriptionA case of occupational dermatitis was reported in a chemical technician, with no cross reactivity to pyridine derivatives.
Chemical PropertiesOff-white crystal
Uses2,2';6',2"-terpyridine is widely utilized in the field of supramolecular chemistry, which is used to manufacture the racks, ladders and grids, helicates, catenanes and dendrimers. It plays an important role as a ligand in coordination chemistry. Its complexes are employed in the oxidation of alcohols, the carbonylation of aromatic compounds and as oxygen-binding molecules. Functionalized terpyridine ligands were used in semiconductors and solar panels. It forms chealate complexes with europium(III) and terbium(III), which is used in protein labelling.
DefinitionChEBI: A tridentate heterocyclic ligand that binds metals at three meridional sites giving two adjacent 5-membered MN2C2 chelate rings.
Synthesis Reference(s)Journal of the American Chemical Society, 103, p. 3585, 1981 DOI: 10.1021/ja00402a062
Organic Syntheses, Coll. Vol. 7, p. 476, 1990
General Description2,2′:6′,2′′;-Terpyridine is a tridentate ligand that can be prepared in two steps starting from 2-acetylpyridine.
Contact allergensThis molecule is a terpyridine with a 4-methyl substitution. A case of occupational dermatitis was reported in a chemical technician with no cross-reactivity to pyridine derivatives.
Purification MethodsCrystallise it from diethyl ether, toluene or from pet ether, then aqueous MeOH, followed by sublimation in a vacuum at 90o. It is used for estimating Ag and Ru. [Kamra et al. Anal Chim Acta 81 177 1976, Beilstein 26 III/IV 258.]
[2,2':6',2''-TERPYRIDINE]-3',4'-DICARBOXYLIC ACID 2,2':6',2''-TERPYRIDINE-4'-CARBOXYLIC ACID 2,2':6',2''-TERPYRIDINE DICHLORO(2 2':6' 2''-TERPYRIDINE)- 6,6''-DIMETHYL-[2,2':6',2''-TERPYRIDINE]-4'-CARBOXYLIC ACID ETHYL ESTER ETHYL 2,2':6',2''-TERPYRIDINE-4'-CARBOXYLATE 6,6''-DIBROMO-2,2':6',2''-TERPYRIDINE,6,6-DIBROMO-2,2:6,2-TERPYRIDINE 4',4''''-(1,4-PHENYLENE)BIS(2,2':6',2''-TERPYRIDINE) 4,4',4''-TRI-TERT-BUTYL-2,2':6',2''-TERPYRIDINE 5-METHYL-4'-NITRO-2,2':6',2''-TERPYRIDINE 4,4-DIMETHYL-4-(4-METHYLPHENYL)-2,2:6,2- TERPYRIDINE 4'-CHLORO-2,2':6',2''-TERPYRIDINE,4'-CHLORO-2,2'6'2''-TERPYRIDINE CHLORO(2,2':6',2''-TERPYRIDINE)PLATINUM(II) CHLORIDE DIHYDRATE,DICHLORO(2,2':6',2''-TERPYRIDINE)PLATINUM(II) DIHYDRATE 6,6''-DIETHOXY-[3,2':5',3'']-TERPYRIDINE 4',5,5''-TRIMETHYL-2,2':6',2''-TERPYRIDINE TRIS(2,2',2''-TERPYRIDINE) RUTHENIUM (II) CHLORIDE 2,2':6',2'':6'',2''':6''',2''''-Quinquepyridine-4''-carboxylic acid ethyl ester BIS-(2,2',2''-TERPYRIDINE) RUTHENIUM (II) CHLORIDE

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