3-HEXYN-1-OL

3-HEXYN-1-OL Basic information
Product Name:3-HEXYN-1-OL
Synonyms:3-Hexyne-1-ol;3-Hexynol;3-HEXYN-1-OL;3-Hexyn-1-ol, 98 %;3-Hexyn-1-ol, 98% 5ML;hex-3-yn-1-ol;3-Hexyn-1-ol 98%;3-HEXYN-1-OL, 98%3-HEXYN-1-OL, 98%3-HEXYN-1-OL, 98%
CAS:1002-28-4
MF:C6H10O
MW:98.14
EINECS:213-685-8
Product Categories:Organic Building Blocks;Acetylenes;Acetylenic Alcohols & Their Derivatives;Alkynes;Internal;Organic Building Blocks;Building Blocks;Chemical Synthesis
Mol File:1002-28-4.mol
3-HEXYN-1-OL Structure
3-HEXYN-1-OL Chemical Properties
Melting point -34°C (estimate)
Boiling point 63-64 °C12 mm Hg(lit.)
density 0.898 g/mL at 25 °C(lit.)
refractive index n20/D 1.454(lit.)
Fp 146 °F
storage temp. 2-8°C
pka14.35±0.10(Predicted)
form clear liquid
color Colorless to Light yellow to Light orange
Specific Gravity0.898
BRN 1735911
CAS DataBase Reference1002-28-4(CAS DataBase Reference)
EPA Substance Registry System3-Hexyn-1-ol (1002-28-4)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36/37/39
WGK Germany 3
HS Code 29052990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
3-HEXYN-1-OL Usage And Synthesis
Chemical PropertiesCLEAR YELLOW LIQUID
Uses3-Hexyn-1-ol is an unsaturated alcohol that, when subjected to stereoselective hydrogenation, produces cis-3-Hexen-1-ol (H295005), a compound that is important in the fragrance industry. 3-Hexyn-1-ol also exhibits antifungal properties against Aspergillus oryzae, a fungus that is used to produce fermented foods and beverages in Japan.
Synthesis Reference(s)Tetrahedron Letters, 18, p. 1019, 1977 DOI: 10.1016/S0040-4039(01)92817-5
General DescriptionThe stereoselective hydrogenation of 3-hexyn-1-ol was studied. Poly(N-vinyl-2-pyrrolidone)-stabilized Pd-nanoclusters showed an extraordinary catalytic performance in the selective hydrogenation of 3-hexyn-1-ol.
3-HEXYN-1-OL Preparation Products And Raw materials
Preparation Productstrans-2-Hexen-1-ol-->TRANS-3-HEXEN-1-OL-->CIS-3-HEXENOIC ACID-->Leaf alcohol-->3-Hexyne, 1-iodo--->(Z)-3,4-dideuteriohex-3-en-1-ol-->(Z)-3,4-dideuteriohex-3-enal-->3-Hexynyl bromide
oxirapentyn 1,3-BIS(1'-HYDROXYCYCLOHEXYL)-1-PROPYNE 3-TETRADECYN-1-OL 3-HEXYN-1-OL 4-OCTYN-2-OL 5-OCTYN-3-OL 2-HEX-1-YNYL-2-METHYL-OXIRANE 3-HEXYN-1,6-DIOL 5-NONYN-3-OL 5-METHYL-3-HEXYN-1-OL 1-Methyl-4-piperidyl phenyl(3-methyl-1-pentynyl)glycolate GOLFOMYCIN A Cicaprost 3-Quinuclidyl phenyl(3-methyl-1-pentynyl)glycolate A 2,5-DIMETHYL-1,2,5,6-DIEPOXYHEX-3-YNE 5-METHYL-5-HEXEN-3-YN-1-OL 6-METHYL-6-HEPTEN-4-YN-2-OL Eptaloprost

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