PALLADIUM(II) TRIFLUOROACETATE

PALLADIUM(II) TRIFLUOROACETATE Basic information
Product Name:PALLADIUM(II) TRIFLUOROACETATE
Synonyms:Palladium(II) trifluoroacetate Vetec(TM) reagent grade, 97%;Palladium(II) trifluoroacetate, 97% trace metals basis;Palldium (II)Trifluoroacetate;PALLADIUM(II) TRIFLUOROACETATE;TRIFLUOROACETIC ACID PALLADIUM(II) SALT;2,7-DICHLORO-9-FLUORENONE, TECH., 90%;PALLADIUM (II) TRIFLUOROACETATE 97+%;Palladium(II) trifluoroacetate, 99+%
CAS:42196-31-6
MF:C4F6O4Pd
MW:332.45
EINECS:
Product Categories:Pd;metal acetate salt
Mol File:42196-31-6.mol
PALLADIUM(II) TRIFLUOROACETATE Structure
PALLADIUM(II) TRIFLUOROACETATE Chemical Properties
Melting point ~220 °C
storage temp. Inert atmosphere,Room Temperature
solubility Soluble in diethyl ether and acetone. Insoluble in benzene, chloroform and trifluoroacetic acid.
form Powder
color Brown
Sensitive Hygroscopic
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
InChIKeyWEJWWPJAIXRLIJ-UHFFFAOYSA-M
CAS DataBase Reference42196-31-6(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
3-10
Hazard Note Irritant
TSCA No
HS Code 28439000
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
PALLADIUM(II) TRIFLUOROACETATE Usage And Synthesis
Chemical Propertiestan to brown powder
UsesApplication Guide for Palladium Catalyzed Cross-Coupling Reactions
UsesPalladium(II) Trifluoroacetate is a pallaium salt of Trifluoroacetic Acid (T786035), a solvent used in a variety of organic synthesis and chemical processes. Also used in the synthesis of anticancer agents as well as phospholipase D inhibitors.
Purification MethodsSuspend it in trifluoroacetic acid and evaporate it on a steam bath a couple of times. The residue is then dried in vacuum (40-80o) to give a brown powder. It is hygroscopic. [Stephenson et al. J Chem Soc 3632 1965, Trost & Metzner J Am Chem Soc 102 3572 1980.]
PALLADIUM(II) TRIFLUOROACETATE Preparation Products And Raw materials
INDIUM TRIFLUOROACETATE Palladium nitrate Palladium (II) Acetate 2-Bromoethyl trifluoromethanesulphonate 2,2-DIFLUOROETHYL TRIFLUOROMETHANESULFONATE Bis(2,4-pentanedionato-O,O')palladium(II) Sodium trifluoroacetate Adapalene Palladium chloride Palladium pivalate 97% FERROUS SULFATE Sodium ascorbate Mercuric trifluoroacetate PALLADIUM(II) TRIFLUOROACETATE 9-Fluorenone Difluoroacetic acid Palladium hydroxide Fluoroacetic acid

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