THALLIUM(I) FLUORIDE

THALLIUM(I) FLUORIDE Basic information
Preparation
Product Name:THALLIUM(I) FLUORIDE
Synonyms:Thallium(I)fluoride,99%;Thallium(I) fluoride 99%;TALLIUM() FLUORIDE;THALLIUM FLUORIDE;THALLIUM FLUORIDE (OUS);THALLIUM(I) FLUORIDE;THALLOUS FLUORIDE;THALLIUM (OUS) FLUORIDE
CAS:7789-27-7
MF:FTl
MW:223.38
EINECS:232-154-1
Product Categories:metal halide
Mol File:7789-27-7.mol
THALLIUM(I) FLUORIDE Structure
THALLIUM(I) FLUORIDE Chemical Properties
Melting point 322 °C(lit.)
Boiling point 655 °C
density 8.3 g/mL at 25 °C(lit.)
Fp 655°C
form Powder
Specific Gravity8.23
color White
Water Solubility Very soluble in water
Merck 14,9262
Exposure limitsACGIH: TWA 0.02 mg/m3; TWA 2.5 mg/m3 (Skin)
NIOSH: IDLH 15 mg/m3; IDLH 250 mg/m3; TWA 0.1 mg/m3
CAS DataBase Reference7789-27-7(CAS DataBase Reference)
EPA Substance Registry SystemThallium fluoride (TlF) (7789-27-7)
Safety Information
Hazard Codes T+,N,T
Risk Statements 26/28-33-51/53
Safety Statements 13-28-45-61
RIDADR UN 1707 6.1/PG 2
WGK Germany 3
RTECS XG4900000
Hazard Note Toxic
TSCA T
HazardClass 6.1
PackingGroup II
HS Code 28261990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
THALLIUM(I) FLUORIDE Usage And Synthesis
PreparationThallium fluoride is prepared by reacting thallium carbonate with hydrofluoric acid. Also, the compound can be made by reacting thallium metal with fluorine.
Chemical Propertieswhite powder(s); ortho-rhomb; hard, shiny crystal(s); can deliquescent, e.g., if breathed upon, however reverts to anhydrous form in dry air; not typically hygroscopic; enthalpy of fusion 14.00kJ/mol [MER06] [STR93] [CRC10]
Physical propertiesHard shiny crystals; orthorhombic structure; density 8.23 g/cm3 at 4°C; melts at 327°C; begins to sublime at 300°C; vaporizes at 655°C; very soluble in water, 78.6 g/100mL at 15°C; decomposes in hot water; slightly soluble in alcohol.
UsesIn the preparation of fluoro esters.
UsesThallium(I) fluoride is used as chemical reagents, fine chemicals, pharmaceutical research and development.
HazardHighly toxic (See Thallium).
Safety ProfilePoison by ingestion. When heated to decomposition it emits very toxic fumes of Fand T1. See also THALLIUM COMPOUNDS and FLUORIDES.
THALLIUM(I) FLUORIDE Preparation Products And Raw materials
THALLIUM (I) TRIFLUOROMETHANESULFONATE THALLIUM(III) TRIFLUOROACETATE THALLIC ACETATE SESQUIHYDRATE THALLIUM(I) BROMIDE THALLIUM(I) 2,4-PENTANEDIONATE Thallium chlorate THALLIUM(I) IODIDE THALLIUM(I) CARBONATE/ 99.9% CYCLOPENTADIENYLTHALLIUM THALLIUM (I) 2-ETHYLHEXANOATE THALLIUM HYDROTRIS[3-(2-PYRIDYL)PYRAZOL-1-YL]BORATE THALLIUM HEXAFLUOROPHOSPHATE THALLIUM(I) HEXAFLUOROACETYLACETONATE THALLIUM 2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE THALLIUM(III) PERCHLORATE HYDRATE THALLIUM (I) PERCHLORATE THALLIUM(I) FLUORIDE THALLIUM (IC) FLUORIDE,THALLIUM(III) FLUORIDE,THALLIUM(III) FLUORIDE 99%,Thallium(III)fluoride99%

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