Ethyl 2-bromopropionate

Ethyl 2-bromopropionate Basic information

Product Name:	Ethyl 2-bromopropionate
Synonyms:	2-bromo-propanoicaciethylester;Ethyl 2-broMopropion;Ethyl 2-broMopropionate 99%;Ethyl 2-bromopropiote;Ethyl-bromopropanoate;Propanoicacid,2-bromo-,ethylester;Propionic acid, 2-bromo-, ethyl ester;2-BROMOPROPANOIC ACID ETHYL ESTER
CAS:	535-11-5
MF:	C5H9BrO2
MW:	181.03
EINECS:	208-609-5
Product Categories:	Esters;ACID BASED BROMO COMPOUNDS;C2 to C5;Carbonyl Compounds;Building Blocks;C2 to C5;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;ester series
Mol File:	535-11-5.mol

Ethyl 2-bromopropionate Chemical Properties

Melting point	<25 °C
Boiling point	156-160 °C (lit.)
density	1.394 g/mL at 25 °C (lit.)
refractive index	n20/D 1.446(lit.)
Fp	125 °F
storage temp.	Store below +30°C.
solubility	Chloroform (Slightly), Methanol (Slightly)
form	Liquid
color	Clear colorless to very slightly yellow
Water Solubility	Immiscible
Merck	14,3772
BRN	773920
Stability:	Corrosive
InChIKey	ARFLASKVLJTEJD-UHFFFAOYSA-N
CAS DataBase Reference	535-11-5(CAS DataBase Reference)
NIST Chemistry Reference	Propanoic acid, 2-bromo-, ethyl ester(535-11-5)
EPA Substance Registry System	Propanoic acid, 2-bromo-, ethyl ester (535-11-5)

Safety Information

Hazard Codes	C,Xn
Risk Statements	10-34-36/37/38-20/22
Safety Statements	16-26-36/37/39-45-37/39
RIDADR	UN 2920 8/PG 2
WGK Germany	3
RTECS	UA2451730
F	8-19
TSCA	Yes
HazardClass	3
PackingGroup	III
HS Code	29159080
Toxicity	LD50 orally in Rabbit: 281 mg/kg

MSDS Information

Provider	Language
2-Bromopropanoic acid ethyl ester	English
SigmaAldrich	English
ACROS	English
ALFA	English

Ethyl 2-bromopropionate Usage And Synthesis

Chemical Properties	clear colorless to very slightly yellow liquid
Uses	Ethyl 2-Bromopropionate is an intermediate in the synthesis of organic compounds and pharmaceuticals.
Uses	It?s an important organic intermediate can be used in agrochemical, pharmaceutical synthesis and dyestuff field.
Purification Methods	Wash the ester with saturated aqueous Na2CO3 (three times), 50% aqueous CaCl2 (three times) and saturated aqueous NaCl (twice). Dry with MgSO4, CaCl2 or CaCO3, and distil it. [Beils

Ethyl 2-bromopropionate Preparation Products And Raw materials

Raw materials	Ethanol-->Thionyl chloride-->Propionic acid-->2-Bromopropionyl chloride
Preparation Products	5-METHYLPYRIMIDIN-4-OL-->4-Hydroxy-5-methyl-2-mercaptopyrimidine-->2-(2,4,5-TRICHLOROPHENOXY)PROPIONIC ACID-->2-(2-OXO-2H-CHROMEN-7-YLOXY)-PROPIONIC ACID-->Oxiracetam-->4-CHLORO-5-METHYL-2-METHYLSULFANYL-PYRIMIDINE-->4(3H)-Pyrimidinone, 5-methyl-2-(methylthio)-

1-BROMO-CYCLOBUTANECARBOXYLIC ACID ETHYL ESTER Ethyl 2-bromovalerate Ethyl 2-bromo-3-oxo-3-phenylpropanoate ETHYL BROMOACETATE-2-13C (R)-(+)-2-BROMOPROPIONIC ACID ETHYL 3-BROMOPROPIONATE, (3-BROMOPROPIONIC ACID ETHYL ESTER) Ethyl BroMoacetate-1,2-13C2 DL-Ethyl 2-bromobutyrate ETHYL 3-BROMOPROPIONATE, [2,3-14C] ISOXADIFEN-ETHYL ETHYL 2-BROMOPROPIONATE, (2-BROMOPROPIONIC ACID ETHYL ESTER) Ethyl 2-bromoheptanoate ETHYL 3-BROMOPROPIONATE-2,2,3,3-D4 ALPHA-BROMO-GAMMA-VALEROLACTONE 5-BROMO-2.2.5-TRIMETHYL-1.3-DIOXANE-4.6-DIONE ETHYL-3-BROMOPROPIONATE-D4 bromoacetoacetic acid ethyl ester DIETHYL BROMOMALONATE

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