5-ETHYLIDENE-2-NORBORNENE

5-ETHYLIDENE-2-NORBORNENE Basic information
Product Name:5-ETHYLIDENE-2-NORBORNENE
Synonyms:ETHYLIDENE NORBORNENE;ETHYLIDENE-2-NORBORNENE;(5E)-5-Ethylidenebicyclo[2.2.1]hept-2-ene;2-Norbornene, 5-ethylidene-;2-norbornene,5-ethylidene-;5-Ethylidene bicyclo[2,2,1]heptene;5-ethylidene-2-norbornen;bicyclo[2.2.1]hept-2-ene,5-ethylidene-
CAS:16219-75-3
MF:C9H12
MW:120.19
EINECS:240-347-7
Product Categories:Acyclic;Alkenes;Organic Building Blocks
Mol File:16219-75-3.mol
5-ETHYLIDENE-2-NORBORNENE Structure
5-ETHYLIDENE-2-NORBORNENE Chemical Properties
Melting point -80.15°C
Boiling point 146 °C(lit.)
density 0.893 g/mL at 25 °C(lit.)
vapor density 4.1 (vs air)
vapor pressure 4.6 mm Hg ( 20 °C)
refractive index n20/D 1.49(lit.)
Fp 101 °F
storage temp. Flammables area
solubility Chloroform (Slightly), Hexanes (Slightly)
form Liquid
color Colorless to Almost colorless
explosive limit~6.4%
Water Solubility Soluble in water (0.01% at 20C).
Exposure limitsACGIH: TWA 2 ppm; STEL 4 ppm
NIOSH: Ceiling 5 ppm(25 mg/m3)
Stability:Volatile
LogP3.82 at 20℃
CAS DataBase Reference16219-75-3(CAS DataBase Reference)
EPA Substance Registry System5-Ethylidene-2-norbornene (16219-75-3)
Safety Information
Hazard Codes Xn,N
Risk Statements 10-22-36/37/38-65-51/53-48/20-43-38-20
Safety Statements 16-26-36/37/39-62-61
RIDADR UN 2929 6.1/PG 2
WGK Germany 2
RTECS RB9450000
TSCA Yes
HazardClass 3
PackingGroup III
HS Code 29021990
Hazardous Substances Data16219-75-3(Hazardous Substances Data)
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
5-ETHYLIDENE-2-NORBORNENE Usage And Synthesis
Chemical Properties5-Ethylidene- 2-norbornene is a colorless liquid with a turpentine-like odor. The Odor Threshold is 0.007 ppm.
Chemical Propertiesclear colorless to yellow liquid
Uses5-Ethylidene-2-norbornene is used as a self healing agent for polymeric composites. It is also used to reinforce multiwalled carbon nanotubes.
UsesAs third monomer in EPDM (ethylene- propylene diene monomer)
UsesEthylidene norbornene is the third monomer in EPDM (ethylene–propylene diene monomer) elastomers.
DefinitionA diene used as the third monomer in EPDM elastomers.
General DescriptionColorless liquid with an odor of turpentine. Flash point 101°F. Floats on water.
Air & Water ReactionsFlammable. Insoluble in water.
Reactivity Profile5-ETHYLIDENE-2-NORBORNENE may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas. In the presence of various catalysts (such as acids) or initiators, may undergo exothermic addition polymerization reactions.
HazardToxic.
Health HazardInhalation of vapors causes headache, confusion, and respiratory distress. Ingestion causes irritation of entire digestive system. Aspiration causes severe pneumonia. Contact with liquid causes irritation of eyes and skin.
Fire Hazard5-ETHYLIDENE-2-NORBORNENE is flammable.
Safety ProfileModerately toxic by ingestion. Mildly toxic by inhalation and sh contact. Human systemic effects by inhalation: conjunctiva, olfactory, and taste changes. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
Potential Exposure5-Ethylidene-2-norbornene is used as the third monomer in terpolymer elastomers. Those engaged in the synthesis of pharmaceuticals; pesticides, or in the preparation of specialty resins.
ShippingUN1993 Flammable liquids, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, Technical Name Required.
IncompatibilitiesMay form explosive mixture with air. Reacts violently with strong oxidants. Violent reaction with oxygen and strong oxidizers. May accumulate static electrical charges, and may cause ignition of its vapors. The substance may polymerize. Inhibit peroxide formation with tert-butyl catechol. ENB should be stored in a nitrogen atmosphere since it reacts with oxygen
Waste DisposalDissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.
5-ETHYLIDENE-2-NORBORNENE Preparation Products And Raw materials
Raw materialsCalcium oxide-->1,3-Butadiene-->1,3-Cyclopentadiene-->Dicyclopentadiene-->Norbornene-->3-Chloro-1-butene
Adamantane Sodium decyl-sulfonate Sodium p-styrenesulfonate Dicyclopentadiene Sulfamic acid 4-Allylanisole Norbornene 5-ETHYLIDENE-2-NORBORNENE 4-tert-Butylcatechol 5-ETHYLIDENE-2-NORBORNENE, POLYMER WITH ETHYLENE AND PROPENE) 5-METHYLENE-2-NORBORNENE Comphene Camphene

Email:[email protected] [email protected]
Copyright © 2024 Mywellwork.com All rights reserved.