SILICON TETRABROMIDE

SILICON TETRABROMIDE Basic information
Product Name:SILICON TETRABROMIDE
Synonyms:SILICON TETRABROMIDE;SILICON(IV) BROMIDE;Silicon(IV) bromide(tetrabromosilane);SILICON BROMIDE;SiBr4;Silane, tetrabromo-;Silane,tetrabromo-;tetrabromo-silan
CAS:7789-66-4
MF:Br4Si
MW:347.7
EINECS:232-182-4
Product Categories:metal halide
Mol File:7789-66-4.mol
SILICON TETRABROMIDE Structure
SILICON TETRABROMIDE Chemical Properties
Melting point 5 °C (lit.)
Boiling point 153 °C (lit.)
density 2.8 g/mL at 25 °C (lit.)
vapor density 2.8 (vs air)
refractive index 1.5627
Fp 154°C
form Liquid
Specific Gravity2.772
color Colorless to pale yellow
Water Solubility decomposed in water to HBr, silicic acid, with evolution of heat [MER06]
Sensitive Moisture Sensitive
Hydrolytic Sensitivity8: reacts rapidly with moisture, water, protic solvents
Merck 14,8499
CAS DataBase Reference7789-66-4(CAS DataBase Reference)
EPA Substance Registry SystemTetrabromosilane (7789-66-4)
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 26-27-28-36/37/39
RIDADR UN 3264 8/PG 2
WGK Germany 3
10-23
TSCA Yes
HazardClass 8
PackingGroup II
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
SILICON TETRABROMIDE Usage And Synthesis
Chemical PropertiesFuming, colorless liquid that turns yel- low in air; disagreeable odor. Decomposed by water with evolution of heat. Noncombustible.
UsesSilicon tetrabromide (SiBr4) may be used to prepare photoluminescent silicon nanocrystals by chemical reduction with alkaline metals.
HazardStrong irritant to tissue.
SILICON TETRABROMIDE Preparation Products And Raw materials
Preparation ProductsTETRAKIS(DIMETHYLAMINO)SILANE
Silicon monoxide Barium iodide Silicon carbide SILICON TETRAACETATE MAGNESIUM BROMIDE DIETHYL ETHERATE SILICON DISULFIDE SILVER BROMIDE Ferrous chloride 1,2-Dibromoethane Tetrachlorosilane SILICON (IV) IODIDE Iodine pentafluoride Cobalt chloride Hydrogen fluoride Magnesium fluoride Magnesium oxide Magnesium chloride SILICON TETRABROMIDE

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