ChemicalBook Product Catalog Chemical Reagents Silane reagent LITHIUM TRIMETHYLSILANOLATE

LITHIUM TRIMETHYLSILANOLATE

LITHIUM TRIMETHYLSILANOLATE Basic information
Product Name:LITHIUM TRIMETHYLSILANOLATE
Synonyms:trimethyl-silanolithiumderivative;trimethylsilanollithiumderiv.;LITHIUM TRIMETHYLSILANOLATE, 1.0M SOLUTI ON IN DICHLOROMETHANE;Lithiumtrimethylsilanolatepure;lithium trimethylsilanolate solution;LITHIUM TRIMETHYLSILANOLATE;Trimethylsiloxylithium;Lithium trimethylsiloxide
CAS:2004-14-0
MF:C3H9LiOSi
MW:96.13
EINECS:
Product Categories:Chemical Synthesis;Organic Bases;Synthetic Reagents
Mol File:2004-14-0.mol
LITHIUM TRIMETHYLSILANOLATE Structure
LITHIUM TRIMETHYLSILANOLATE Chemical Properties
Boiling point 40 °C
density 1.278 g/mL at 25 °C
vapor pressure 24.12 psi ( 55 °C)
Fp 145 °F
Specific Gravity0.876
Hydrolytic Sensitivity7: reacts slowly with moisture/water
BRN 3686900
Safety Information
Hazard Codes C,T
Risk Statements 34-40-23/24/25
Safety Statements 26-28-36/37/39-45-27-16
RIDADR UN 3267 8/PG 2
WGK Germany 3
RTECS VV7175000
F 10-21
TSCA No
HazardClass 8
PackingGroup III
HS Code 29310099
MSDS Information
ProviderLanguage
SigmaAldrich English
LITHIUM TRIMETHYLSILANOLATE Usage And Synthesis
Purification MethodsWash it with Et2O and pet ether. It sublimes at 180o/1mm as fine transparent needles. [Tatlock & Rochnow J Org Chem 17 1555 1952, Beilstein 4 IV 3992.] Suspected CARCINOGEN.
LITHIUM TRIMETHYLSILANOLATE Preparation Products And Raw materials
Preparation ProductsN-(Trimethylsilyl)-2,2-dimethylpropane-1-imine-->1-Phospha-1-butyne, 3,3-dimethyl--->1-Butene, 1-bromo-3-methyl--->1-(1,1 -Dimethylethoxy)butane-->Hydrogen-->1-BUTENE
Potassium trimethylsilanolate hydroxytrimethylsilane 2,2-DiMethyl-3-oxo-pyrrolidine-1-carboxylicacidethylester LITHIUM TRIMETHYLSILANOLATE Lithium silicon Lithium
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