ChemicalBook Product Catalog Chemical Reagents Organic reagents The polycyclic compound 9-Anthracenemethanol

9-Anthracenemethanol

9-Anthracenemethanol Basic information
Product Name:9-Anthracenemethanol
Synonyms:9-ANTHRACENEMETHANOL;9-ANTHRACENE METHYL CARBINOL;9-(HYDROXYMETHYL)ANTHRACENE;ANTHRACENE-9-METHANOL;AKOS B023870;ART-CHEM-BB B023870;RARECHEM AL BD 0006;9-Anthracene carbinol
CAS:1468-95-7
MF:C15H12O
MW:208.26
EINECS:215-998-5
Product Categories:Anthracene series;Halogenated Heterocycles ,Pyrimidines;Alcohols;Building Blocks;C11 to C30+;Chemical Synthesis;Organic Building Blocks;Oxygen Compounds;Aromatic alcohols and diols;Alkohols;Electronic Chemicals;Anthracenes;bc0001
Mol File:1468-95-7.mol
9-Anthracenemethanol Structure
9-Anthracenemethanol Chemical Properties
Melting point 162-164 °C(lit.)
Boiling point 307.46°C (rough estimate)
density 1.0459 (rough estimate)
refractive index 1.5361 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility Soluble in hot methanol very faint turbidity.
form Crystalline Powder
pka14.36±0.10(Predicted)
color Yellow
BRN 1873402
Stability:Stable. Incompatible with oxidizing agents.
InChIKeyJCJNNHDZTLRSGN-UHFFFAOYSA-N
CAS DataBase Reference1468-95-7(CAS DataBase Reference)
NIST Chemistry Reference9-Anthracenemethanol(1468-95-7)
EPA Substance Registry System9-Anthracenemethanol (1468-95-7)
Safety Information
Risk Statements 20/21/22-36/37/38
Safety Statements 24/25
WGK Germany 3
RTECS CB0577500
TSCA Yes
HS Code 29062900
Toxicitymic-bac-sat 390 mmol/L CRNGDP 15,2605,94
MSDS Information
ProviderLanguage
9-Anthracenemethanol English
SigmaAldrich English
ACROS English
ALFA English
9-Anthracenemethanol Usage And Synthesis
Chemical PropertiesIt is a colorless or light yellow solid that is soluble in ordinary organic solvents.
UsesAn anthracene derivative used in Diels-Alder reactions. Also used in the preparation of 9-anthracenylmethyl-1-piperazinecarboxylate.
Uses9-Anthracenemethanol can be used:
As a starting material to prepare 9-anthracenylmethyl-1-piperazinecarboxylate, which acts as a reagent in the determination of isocyanates using HPLC.
In the Diels-Alder reaction with dimethylacetylene-dicarboxylate to yield lactone derivatives.
As an initiator in the ring-opening polymerization of δ-valerolactone to yield poly(δ-valerolactone).
As a starting material in the synthesis of polymer-supported anthracene, which acts as a dienophile scavenger in cycloaddition reactions.
Preparation9-Anthracenemethanol is synthesized by hydrogenation of 9-anthracenecarboxaldehyde. It is a versatile precursor to supramolecular assemblies.
General Description9-Anthracenemethanol participates in ring-opening polymerization of L-lactide catalyzed by alumoxane. It undergoes proton exchange reaction with potassium tert-butoxide to yield potassium 9-anthracenemethoxide.
Safety ProfileMutation data reported. Whenheated to decomposition it emits acrid smoke andirritating vapors.
9-Anthracenemethanol Preparation Products And Raw materials
Raw materialsTetrahydrofuran-->Sodium borohydride-->9-Anthraldehyde
Preparation Products9-(Chloromethyl)anthracene-->9-Anthracenylmethyl methacrylate
6-BENZOYLOXYMETHYLBENZO(A)PYRENE CHOLESTERYL 9-ANTHRACENECARBOXYLATE 6-(hydroxymethyl)benzo(a)pyrene RARECHEM AL BP 0006 6-sulfooxymethylbenzo(a)pyrene HYPOCRELLIN A 9-Anthracenylmethyl methacrylate ANTHRYLMETHYL OKADAATE (R)-α-(Trifluoromethyl)-9-anthracenemethanol,(R)-(-)-ALPHA-(TRIFLUOROMETHYL)-9-ANTHRACENEMETHANOL,ALPHA-(TRIFLUOROMETHYL)-9-ANTHRACENEMETHANOL 1-Acetoxy-3-methylcholanthrene RARECHEM AL BD 0570 benzo(a)pyrene 11,12-oxide 6-acetoxymethylbenzo(a)pyrene anthracene-1,5-dicarboxylic acid 9-ANTHROYL OUABAIN ALPHA-(TRIFLUOROMETHYL)-9-ANTHRACENEMETHANOL RARECHEM AL BF 0006 RARECHEM AL BE 0530
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