Strontium chromate

Strontium chromate Basic information
Product Name:Strontium chromate
Synonyms:c.i.pigmentyellow32;chromicacid(h2cro4),strontiumsalt(1:1);Chromicacid,strontiumsalt(1:1);deeplemonyellow;strontiumchromate(1:1);strontiumchromate(srcro4);strontiumchromate(vi);strontiumchromate12170
CAS:7789-06-2
MF:CrO4Sr
MW:203.61
EINECS:232-142-6
Product Categories:Inorganic Chemicals;Inorganics
Mol File:7789-06-2.mol
Strontium chromate Structure
Strontium chromate Chemical Properties
Melting point decomposes [KIR78]
density 3.895
form Powder
Specific Gravity3.895
Water Solubility Soluble in boiling water, dilute HCl, dilute CH{3}CO{2}H
Merck 14,8841
Solubility Product Constant (Ksp)pKsp: 4.65
Exposure limitsACGIH: TWA 0.0002 mg/m3; STEL 0.0005 mg/m3 (Skin)
OSHA: Ceiling 0.1 mg/m3
NIOSH: IDLH 15 mg/m3; TWA 0.0002 mg/m3
Stability:Stability
CAS DataBase Reference7789-06-2(CAS DataBase Reference)
EPA Substance Registry SystemStrontium chromate (7789-06-2)
Safety Information
Hazard Codes T,N
Risk Statements 45-22-50/53
Safety Statements 53-45-60-61
RIDADR UN3087
TSCA Yes
HazardClass 5.1
PackingGroup III
Hazardous Substances Data7789-06-2(Hazardous Substances Data)
MSDS Information
ProviderLanguage
ALFA English
Strontium chromate Usage And Synthesis
Chemical PropertiesStrontium chromate a light yellow crystalline solid or powder.
Strontium chromate
Strontium chromate is prepared by precipitating a suitably soluble chromate with an appropriate strontium salt. Finding a primary use in corrosion-inhibiting coatings, this pigment has poor tint strength, low opacity, and unsatisfactory alkali and acid resistance, which limits its more widespread use in the coatings industry. Little of this pigment is now manu- factured in the United States.

UsesStrontium Chromate is highly corrosive and a strong oxidizing agent. It’s used in chrome plating, corrosion inhibition, and as a colorant in polyvinyl chloride.
UsesStrontium chromate is mainly used to prevent corrosion on aluminum, and primers containing this pigment are standard for the aviation industry. Strontium chromate is so effective at low loadings that it is often used to provide inhibition for coil coatings despite the fact that it is the most expensive chromate inhibitor. The pigment is sometimes combined with zinc chromate in water-based formulations. In these cases, to avoid stability problems, loadings are kept at low levels, about 2% total chromate.
Corrosion inhibitor in pigments; in electrochemical processes to control sulfate concentration of solutions.
General DescriptionSTRONTIUM CHROMATE is a light yellow powder or granular solid. STRONTIUM CHROMATE is insoluble in water. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. STRONTIUM CHROMATE is used as a pigment, a protective coating against corrosion, and in pyrotechnics.
Air & Water ReactionsSTRONTIUM CHROMATE is insoluble in water. Reactivity in Water: Produces hazardous solution.
Reactivity ProfileOxidizing agents, such as STRONTIUM CHROMATE, can react with reducing agents to generate heat and products that may be gaseous (causing pressurization of closed containers). The products may themselves be capable of further reactions (such as combustion in the air). The chemical reduction of materials in this group can be rapid or even explosive, but often requires initiation (heat, spark, catalyst, addition of a solvent). Explosive mixtures of inorganic oxidizing agents with reducing agents often persist unchanged for long periods if initiation is prevented. Such systems are typically mixtures of solids, but may involve any combination of physical states. Some inorganic oxidizing agents are salts of metals that are soluble in water; dissolution dilutes but does not nullify the oxidizing power of such materials. Organic compounds, in general, have some reducing power and can in principle react with compounds in this class. Actual reactivity varies greatly with the identity of the organic compound. Inorganic oxidizing agents can react violently with active metals, cyanides, esters, and thiocyanates. Avoid contact with water, acids, and bases.
HazardToxic by ingestion. Confirmed carcinogen.
Health HazardINHALATION: Irritating to mucous membranes. SKIN: Repeated skin contact can cause eczematous dermatitis, with edema and ulceration. INGESTION: Dizziness, intense thirst, abdominal pain, vomiting, shock and oliguria or anuria.
Fire HazardBehavior in Fire: Heat stable
Safety ProfileConfirmed human carcinogen with experimental carcinogenic and tumorigenic data. Moderately toxic by ingestion. Mutation data reported. See also CHROMIUM COMPOUNDS and STRONTIUM COMPOUNDS.
Potential ExposureStrontium chromate is used as a metal protective coating to prevent corrosion, in wash primers; and aluminum flake coatings; colorant in polyvinyl chloride resins and pyrotechnics.
ShippingUN3086 Toxic solids, oxidizing, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, 5.1-Oxidizer. Technical Name Required.
Purification MethodsCrystallise strontium chromate from water (40mL/g) by cooling.
Properties and Applications

TEST ITEMS

SPECIFICATION

APPEARANCE

LEMON YELLOW POWDER

SHADE

GREENISH

CONTENT of Sr (SrO)

46.5%

CONTENT of Cr (CrO3)

44.0%

HEAT RESISTANCE

600 °C min

LIGHT FASTNESS

7~8

ACID RESISTANCE

4

ALKALI RESISTANCE

4

FASTNESS TO BLEEDING

5

OIL ABSORPTION

20-28%

DENSITY

3.90 g/cm 3

RESIDUE ON 80 MESH

5.0% max

WATER SOLUBLE

1.0% max

VOLATITE 105 °C

1.0% max

TINTING STRENGTH

100-105 %

IncompatibilitiesViolent reaction with strong oxidizers, hydrazine. Incompatible with combustible, organic, or other readily oxidizable materials, such as paper, wood, sulfur, aluminum powder. Attacks plastics and coatings
Strontium chromate Preparation Products And Raw materials
Raw materialsOxygen-->Sodium dichromate dihydrate-->Strontium chloride
Preparation Products(Strontium-Calcium) Chrome Yellow
Chromic sulfate Nickel chloride Strontium carbonate AMMONIUM MAGNESIUM PHOSPHATE HEXAHYDRATE STRONTIUM Digold trioxide Thickening agent Strontium chloride Strontium sulfate Potassium chromate STRONTIUM ACETATE Magnesium oxide Calcium chloride hexahydrate Strontium hydroxide Barium sulfate Strontium chromate STRONTIUM HYDRIDE (Strontium-Calcium) Chrome Yellow

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