2-Ethylhexyl acrylate

2-Ethylhexyl acrylate Basic information
Product Name:2-Ethylhexyl acrylate
Synonyms:2-ETHYLHEXYL ACRYLATE extrapure;2-Ethylhexyl acrylate ,99% [contains 10-20 ppm MEHQ as inhibitor];2-ETHYLHEXYL ACRYLATE, 99+%, STABILIZED;2-Ethylhexyl acrylate, stabilized;Acrylic acid 2-ethylhexyl;Propenoic acid 2-ethylhexyl ester;2-Ethylhexyl acrylate, stabilized, 99+% 1KG;Acrylic Acid 2-Ethylhexyl Ester Monomer Acrylic Acid Octyl Ester Monomer Octyl Acrylate Monomer
CAS:103-11-7
MF:C11H20O2
MW:184.28
EINECS:203-080-7
Product Categories:Industrial/Fine Chemicals;ester series
Mol File:103-11-7.mol
2-Ethylhexyl acrylate Structure
2-Ethylhexyl acrylate Chemical Properties
Melting point -90°C
Boiling point 215-219 °C(lit.)
density 0.885 g/mL at 25 °C(lit.)
vapor density 6.4 (vs air)
vapor pressure 0.15 mm Hg ( 20 °C)
refractive index n20/D 1.436(lit.)
Fp 175 °F
storage temp. Store below +30°C.
solubility 0.1g/l
form Liquid
color Clear
OdorEster like odour
explosive limit0.9-6.0%(V)
Water Solubility <0.1 g/100 mL at 22 ºC
BRN 1765828
Exposure limitsACGIH: TWA 5 mg/m3
NIOSH: TWA 5 mg/m3
Stability:Stability Stable, but polymerizes readily, so is usually inhibited with hydroquinone or its monomethyl ether. Susceptible to hydrolysis. Combustible. Incompatible with oxidizing agents.
InChIKeyGOXQRTZXKQZDDN-UHFFFAOYSA-N
LogP4 at 20℃
CAS DataBase Reference103-11-7(CAS DataBase Reference)
IARC2B (Vol. 60, 122) 2019
NIST Chemistry Reference2-Propenoic acid, 2-ethylhexyl ester(103-11-7)
EPA Substance Registry System2-Ethylhexyl acrylate (103-11-7)
Safety Information
Hazard Codes Xi
Risk Statements 37/38-43
Safety Statements 36/37-46
RIDADR UN 3334
WGK Germany 1
RTECS AT0855000
10-23
Autoignition Temperature496 °F
TSCA Yes
HS Code 29161290
Hazardous Substances Data103-11-7(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 4435 mg/kg LD50 dermal Rabbit 7522 mg/kg
MSDS Information
ProviderLanguage
2-Propenoic acid octyl ester English
SigmaAldrich English
ACROS English
ALFA English
2-Ethylhexyl acrylate Usage And Synthesis
Chemical PropertiesA colorless and transparent liquid that is nearly insoluble in water but can be mixed with alcohol and ether. It was present in a surgical tape and caused allergic contact dermatitis in a patient.
Uses2-ethylhexyl acrylate is a monomer for plastics, protective coating, paper treatment, water-based paints, UV-curable coatings, and inks; in so me acrylicbased adhesive tapes.
DefinitionChEBI: 2-Ethylhexyl acrylate is an ester of enoic acid. It is commonly used as a plasticizing co-monomer in the production of resins, which are utilized in various applications such as adhesives, latex, paints, textile and leather finishes, and coatings for paper.
Preparation2-Ethylhexyl acrylate is obtained by esterifying acrylic acid and 2-ethylhexanol with sulfuric acid as a catalyst, and subsequently neutralizing, dealcoholizing and rectifying the mixture.
General Description2-ethylhexyl acrylate appears as a clear colorless liquid with a pleasant odor. Less dense than water and insoluble in water. Vapors heavier than air. Flash point 180 °F. Used in making of paints and plastics.
Air & Water ReactionsInsoluble in water.
Reactivity Profile2-Ethylhexyl acrylate polymerizes readily in the presence of heat and light generating much heat; reacts with strong oxidants. REF [Handling Chemicals Safely, 1980. p. 235].
HazardQuestionable carcinogen.
Health HazardInhalation of concentrated vapor causes drowsiness and convulsions. Liquid causes irritation of eyes and may irritate skin on prolonged exposure. Ingestion produces same symptoms as inhalation.
Fire HazardBehavior in Fire: Heat can result in a severe polymerization with rapid release of energy. Sealed containers may rupture explosively if hot.
Flammability and ExplosibilityNotclassified
Potential ExposureA potential danger to those involved in the use of this monomer as a feedstock for chemical syntheses; in the manufacture of plastics; protective coatings, including water-based paints; in paper treatment; the production of emulsion polymers.
IncompatibilitiesUnless inhibited, sunlight, heat, contaminants, or peroxides can cause dangerous polymerization. Vapors are uninhibited and may polymerize, blocking vents. Violent reaction with strong oxidizers, with risk of fire and explosions. May form explosive mixture with air. Incompatible with strong acids; aliphatic amines; alkanolamines.
Waste DisposalSpray into incinerator with added flammable solvent.
2-Ethylhexyl acrylate Preparation Products And Raw materials
Raw materialsMethyl acrylate-->Acrylic acid-->1-Octanol-->2-Ethylhexanol-->(S)-tert-Butyl 6-amino-2-((tert-butoxycarbonyl)amino)hexanoate hydrochloride
Butyl acrylate Acrylic acid Methyl acrylate Ethylhexyl Palmitate URETHANE ACRYLATE 2-Ethylhexyl acrylate Hydroxypropyl acrylate 2-Ethylhexyl acetate Methyl propiolate Olibanum oil Acetic acid octyl ester 2-Ethylhexyl cyanoacetate ETHYLHEXYL ACRYLATE Diisooctyl phthalate BUTYL OLEATE Polyacrylate rubber Polypropylene Dimethyl succinate

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