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Butylmagnesium chloride

Butylmagnesium chloride Basic information
Product Name:Butylmagnesium chloride
Synonyms:n-ButylMagnesiuM chloride, 2.0 M solution in THF, SpcSeal;n-ButylMagnesiuM chloride, 2.0M solution in Diethyl ether, SpcSeal;n-Butylmagnesium chloride, 1.45M solution in Butyl diglyme, HySeal;Butylmagnesium chloride 1.5-2.5M in THF;Butylmagnesium chloride solution 1.45 M in butyl diglyme;Butylmagnesium chloride solution 2.0 M in diethyl ether;Butylmagnesium chloride 2M solution in tetrahydrofuran;n-Butylmagnesium chloride, 1.0 M in 2-MeTHF
CAS:693-04-9
MF:C4H9ClMg
MW:116.87
EINECS:211-739-5
Product Categories:Typical Metal Compounds;AlkylChemical Synthesis;Grignard Reagents;Organic Bases;Organometallic Reagents;Synthetic Reagents;Alkyl;Chemical Synthesis;Organic Bases;Organometallic Reagents;Synthetic Reagents;grignard reagent;Classes of Metal Compounds;Grignard Reagents;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Synthetic Organic Chemistry
Mol File:693-04-9.mol
Butylmagnesium chloride Structure
Butylmagnesium chloride Chemical Properties
Melting point -17°C
Boiling point 66°C
density 0.962 g/mL at 25 °C
Fp 115 °F
storage temp. 2-8°C
form Solution
color Green-brown to brown
Water Solubility reacts
Sensitive Air & Moisture Sensitive
BRN 3587228
InChIKeyUUNGXYVLXYGZKH-UHFFFAOYSA-M
CAS DataBase Reference693-04-9(CAS DataBase Reference)
EPA Substance Registry SystemMagnesium, butylchloro- (693-04-9)
Safety Information
Hazard Codes C,F,F+
Risk Statements 12-14/15-19-22-34-67-65-63-48/20-11-15-14-10-40-37
Safety Statements 7-9-16-26-29-33-36/37/39-43-45-62-46
RIDADR UN 3399 4.3/PG 2
WGK Germany 1
F 10
TSCA Yes
HazardClass 4.3
PackingGroup II
HS Code 29319090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
Butylmagnesium chloride Usage And Synthesis
Chemical Propertiesgreen-brown to brown solution
UsesButylmagnesium chloride (BuMgCl) is a Grignard reagent that can be used:
  • To prevent the formation of passivating surface films on Mg electrodes.
  • For the synthesis of lithium tributylmagnesate complex (n-Bu3MgLi) by reacting with n-BuLi.

Usesn-Butylmagnesium chloride is used in organic synthesis, pharmaceuticals, agrochemicals and dyestuffs.
Butylmagnesium chloride Preparation Products And Raw materials
Preparation Products3-Quinolinecarboxaldehyde-->1-(4-Bromophenyl)hexane-->Tetraethyl orthosilicate-->UNDECANE,5-METHYL--->N,N-Diethyldecanamide-->1-NITROBUTANE-->BUTYLMAGNESIUM DIISOPROPYLAMIDE 1.0 M-->ETHYL 8-OXODODECANOATE-->2-broMo-6-(triMethylsilyl)pyridine
Butyldi-1-adamantylphosphine ZIRCONIUM N-PROPOXIDE N-BUTYLMAGNESIUM BROMIDE DI-N-BUTYLMAGNESIUM CYCLOHEXYLMAGNESIUM CHLORIDE Sodium butanolate Butyltin oxide Tetradecylmagnesium chloride 3-PHENYL-1-PROPYLMAGNESIUM CHLORIDE Magnesium monochloride T-BUTYLMAGNESIUM CHLORIDE 2MIN ETHER OCTYLMAGNESIUM CHLORIDE CYCLOPENTYLMAGNESIUM CHLORIDE 3,3-DIMETHYL-1-BUTYLMAGNESIUM CHLORIDE 3,3-DIMETHYL-1-BUTYLMAGNESIUM CHLORIDE.5M THF OCTADECYLMAGNESIUM CHLORIDE 3-(2,5,5-TRIMETHYL-1,3-DIOXAN-2-YL)PROPYLMAGNESIUM CHLORIDE N-BUTYLMAGNESIUM CHLORIDE (2 M IN THF)
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