1,4-Diamino-2-nitrobenzene

1,4-Diamino-2-nitrobenzene Basic information
Product Name:1,4-Diamino-2-nitrobenzene
Synonyms:4-Amino-2-nitroaniline;4-amino-2-nitroaniline(2-nitro-1,4-phenylenediamine);C.I. 76070;C.I. Oxidation Base 22;c.i.76070;c.i.oxidationbase22;ci76070;cioxidationbase22
CAS:5307-14-2
MF:C6H7N3O2
MW:153.14
EINECS:226-164-5
Product Categories:Building Blocks;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks;Polyamines;Amines;Intermediates of Dyes and Pigments;Anilines, Aromatic Amines and Nitro Compounds
Mol File:5307-14-2.mol
1,4-Diamino-2-nitrobenzene Structure
1,4-Diamino-2-nitrobenzene Chemical Properties
Melting point 135-138 °C (lit.)
Boiling point 276.04°C (rough estimate)
density 1.3682 (rough estimate)
refractive index 1.6500 (estimate)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility 0.2g/l
pka4.36±0.10(Predicted)
form Powder
color Brown to black
PH7 (H2O)(aqueous suspension)
Water Solubility <0.1 g/100 mL at 22 ºC
BRN 2210195
Stability:Stable. Incompatible with strong oxidizing agents.
InChIKeyHVHNMNGARPCGGD-UHFFFAOYSA-N
LogP0.53
CAS DataBase Reference5307-14-2(CAS DataBase Reference)
IARC3 (Vol. Sup 7, 57) 1993
NIST Chemistry Reference1,4-Benzenediamine, 2-nitro-(5307-14-2)
EPA Substance Registry System2-Nitro-p-phenylenediamine (5307-14-2)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 43-68
Safety Statements 36/37-45
RIDADR 3143
WGK Germany 2
RTECS ST3000000
TSCA Yes
HS Code 29215119
Hazardous Substances Data5307-14-2(Hazardous Substances Data)
MSDS Information
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1,4-Diamino-2-nitrobenzene Usage And Synthesis
Descriptiono-Nitro-paraphenylenediamine (ONPD) is a hair dye and a sensitizer in hairdressers.
Chemical PropertiesDark red crystal Powder
UsesThis compound is used in hair and fur dyes.
Uses2-Nitro-4-phenylene-diamine is a dyestuff used to dye furs brown and reddish-brown; dye intermediate in semi-permanent and permanent hair coloring products (produces brown and red shades on the hair); in different hair-dyeing preparations.
DefinitionChEBI: A primary amino compound that is p-phenylenediamine in which one of the hydrogens attached to the benzene ring is replaced by a nitro group. It is a cosmetic hair dye intermediate that is used in permanent hair colouring products (diluted 1:1 ith an oxidising agent prior to application).
General DescriptionAlmost black needles with dark-green luster or black powder.
Air & Water Reactions1,4-Diamino-2-nitrobenzene may be sensitive to prolonged exposure to light and air. Insoluble in water.
Reactivity Profile1,4-Diamino-2-nitrobenzene is incompatible with strong oxidizing agents.
Fire HazardFlash point data for 1,4-Diamino-2-nitrobenzene are not available; however, 1,4-Diamino-2-nitrobenzene is probably combustible.
Flammability and ExplosibilityNonflammable
Contact allergensONPD is a hair dye and a sensitizer in hairdressers and consumers who are generally sensitive to PPD too.
Safety ProfileSuspected carcinogen with experimental carcinogenic and neoplastigenic data. Poison by intraperitoneal route. Moderately toxic by ingestion. An experimental teratogen. Other experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx,.
1,4-Diamino-2-nitrobenzene Preparation Products And Raw materials
Preparation Products4-(4-Fluorobenzylamino)-1,2-phenylenediamine-->5-AMINO-1,3-DIMETHYL-1,3-DIHYDRO-BENZOIMIDAZOL-2-ONE
2,4-DINITRO-5-FLUOROANILINE 2-Nitro-1,4-benzenediamine sulfate 2,3,5,6-TETRAMETHYL-1,4-PHENYLENEDIAMINE 2,7-Naphthalenedisulfonic acid, 4-amino-5-hydroxy-, diazotized, coupled with diazotized 4-nitro-1,3-benzenediamine and resorcinol, potassium sodium salts 4-nitrobenzene-1,2-diamine dihydrochloride 1,3-BENZENEDIAMINE, 2-CHLORO-4-NITRO- 1,3-Diamino-5-nitrobenzene,3,5-Diamino-1-nitrobenzene (1,2-diamino-4-nitrobenzene)dichloroplatinum(II) 1,3-Diamino-2-nitrobenzene,2,6-Diamino-1-nitrobenzene 4,5-DINITRO-O-PHENYLENEDIAMINE,98% 4-(2,4-DINITROANILINO)PHENOL 2,4-Dinitrodiphenylamine 4-Nitro-1,3-phenylenediamine sulfate 1,2-DIAMINO-4-NITROBENZENE MONOHYDROCHLORIDE 4-Amino-3-nitro-6-methylaniline 1,2-DIAMINO-3-NITROBENZENE,1,2-Diamino-3-nitrobenzene, 3-Nitro-o-phenylenediamine,2,3-Diamino-1-nitrobenzene 2,4,6-TRINITROANILINE N-(4-DIMETHYLAMINO-3,5-DINITROPHENYL)MALEIMIDE

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