2-Chlorobenzotrifluoride

2-Chlorobenzotrifluoride Basic information

Product Name:	2-Chlorobenzotrifluoride
Synonyms:	CHLOROBENZOTRIFLUORIDE(O-);2-CHLOROBENZOTRIFLUOROIDE;o-Trifluoromethylphenyl;Toluene, o-chloro-alpha,alpha,alpha-trifluoro-;O-CHLORO(TRIFLUOROMETHYL)BENZENE;O-CHLOROBENZYLIDYNE TRIFLUORIDE;O-CHLOROBENZOTRIFLUORIDE;O-CHLORO-A,A,A-TRIFLUOROTOLUENE
CAS:	88-16-4
MF:	C7H4ClF3
MW:	180.55
EINECS:	201-805-1
Product Categories:	Chlorine Compounds;Fluorine Compounds;Aromatic Hydrocarbons (substituted) & Derivatives
Mol File:	88-16-4.mol

2-Chlorobenzotrifluoride Chemical Properties

Melting point	-7.4 °C
Boiling point	152 °C(lit.)
density	1.379 g/mL at 25 °C(lit.)
refractive index	n20/D 1.456(lit.)
Fp	138 °F
storage temp.	Flammables area
form	clear liquid
color	Colorless to Light yellow
Specific Gravity	1.379
explosive limit	1.7%(V)
Water Solubility	<0.1 g/100 mL at 19.5 ºC
BRN	510993
Exposure limits	ACGIH: TWA 2.5 mg/m3 NIOSH: IDLH 250 mg/m3
Stability:	Stable. Flammable. Incompatible with strong oxidizing agents, strong bases.
CAS DataBase Reference	88-16-4(CAS DataBase Reference)
NIST Chemistry Reference	Benzene, 1-chloro-2-(trifluoromethyl)-(88-16-4)
EPA Substance Registry System	2-Chlorobenzotrifluoride (88-16-4)

Safety Information

Hazard Codes	Xi,F,Xn,N
Risk Statements	10-36/37/38-22
Safety Statements	26-36-36/37/39-16
RIDADR	UN 2234 3/PG 3
WGK Germany	3
RTECS	XS9141000
Hazard Note	Flammable/Irritant
TSCA	T
HazardClass	3
PackingGroup	III
HS Code	29036990

MSDS Information

Provider	Language
2-Chloro-alpha,alpha,alpha-trifluorotoluene	English
SigmaAldrich	English
ACROS	English
ALFA	English

2-Chlorobenzotrifluoride Usage And Synthesis

Chemical Properties	Clear colourless to light yellow liquid
Uses	Dye intermediate, chemical intermediate, solvent, and dielectric fluid.
Purification Methods	Dry the trifluoride over CaSO4, and distil it at high reflux ratio through a silvered vacuum-jacketed glass column packed with one-eight inch glass helices [Potter & Saylor J Am Chem Soc 73 90 1951]. [Beilstein 5 H 302, 5 III 692, 5 IV 814.]

2-Chlorobenzotrifluoride Preparation Products And Raw materials

Raw materials	Chlorine-->Hydrogen fluoride-->2-Chlorotoluene-->ANTIMONY(V) CHLORIDE-->2-Chlorobenzotrichloride
Preparation Products	Fomesafen-->4-Chloro-3-(trifluoromethyl)benzaldehyde-->2-(Trifluoromethyl)benzyl bromide-->2-(Trifluoromethyl)benzoic acid-->1-(2-TRIFLUOROMETHYLPHENYL)-PIPERAZINE-->2-Chloro-3,5-dinitrobenzotrifluoride-->2-Chloro-5-nitrobenzotrifluoride-->2-chloro-1-nitro-3-(trifluoromethyl)benzene-->Methyl 2-(trifluoromethyl)benzoate-->Benzotrifluoride-->(2-Chlorophenyl)phenyl-methanone

2,3-Dibromo-5-chlorobenzotrifluoride 3-FLUORO-4-CHLOROBENZOTRIFLUORIDE 2-CHLORO-4-(TRIFLUOROMETHYL)BENZENE 1-CHLORO-3-(TRIFLUOROMETHYL)BENZENE = M-CHLOROBENZOTRIFLUORIDE 0-CHLOROBENZOTRIFLUORIDE 3-Amino-4-chlorobenzotrifluoride, 6-Chloro-α,α,α-trifluoro-m-toluidine,3-Amino-4-chlorobenzotrifluoride ,97%,3-Amino-4-chlorobenzotrifluoride98% alpha-Chloro-o-fluorotoluene 4-Amino-3-chlorobenzotrifluoride97%,4-Amino-3-chlorobenzotrifluoride 97% 1-BROMO-2-CHLORO-4-TRIFLUOROMETHYL-BENZENE,4-BROMO-3-CHLOROBENZOTRIFLUORIDE ,98% Trifluoromethyl 4-bromo-2-chloro-1-(trifluoromethyl)benzene 2-Amino-5-iodo-3-chlorobenzotrifluoride 2-AMINO-5-BROMO-3-CHLOROBENZOTRIFLUORIDE 2-Cyano-5-chlorobenzotrifluoride 2-AMINO-3-CHLOROBENZOTRIFLUORIDE 2-AMINO-4-CHLOROBENZOTRIFLUORIDE 4-CHLORO-5-TRIFLUOROMETHYL-BENZENE-1,2-DIAMINE 2-AMINO-3-BROMO-5-CHLOROBENZOTRIFLUORIDE

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