n-Hendecane

n-Hendecane Basic information
Product Name:n-Hendecane
Synonyms:HENDECANE;ALKANE C11;Undecane [Standard Material];UNDECANE;hendecane(undecane);n-C11H24;undecanenormal;N-HENDECANE
CAS:1120-21-4
MF:C11H24
MW:156.31
EINECS:214-300-6
Product Categories:n-Paraffins (GC Standard);Standard Materials for GC;Analytical Chemistry
Mol File:1120-21-4.mol
n-Hendecane Structure
n-Hendecane Chemical Properties
Melting point -26 °C (lit.)
Boiling point 196 °C (lit.)
density 0.74 g/mL at 25 °C (lit.)
vapor density 5.4 (vs air)
vapor pressure <0.4 mm Hg ( 20 °C)
refractive index n20/D 1.417(lit.)
Fp 140 °F
storage temp. Store below +30°C.
form Liquid
Specific Gravity0.7402
color Colorless
explosive limit0.6-6.5%(V)
Odor Threshold0.62ppm
Water Solubility IMMISCIBLE
BRN 1697099
InChIKeyRSJKGSCJYJTIGS-UHFFFAOYSA-N
LogP6.312 (est)
CAS DataBase Reference1120-21-4(CAS DataBase Reference)
NIST Chemistry ReferenceUndecane(1120-21-4)
EPA Substance Registry SystemUndecane (1120-21-4)
Safety Information
Hazard Codes Xn
Risk Statements 36/37/38-65-66
Safety Statements 26-36-24/25-62
RIDADR UN 2330 3/PG 3
WGK Germany 3
RTECS YQ1525000
Autoignition Temperature220 °C
TSCA Yes
HazardClass 3
PackingGroup III
HS Code 29011090
Hazardous Substances Data1120-21-4(Hazardous Substances Data)
Toxicitymouse,LD50,intravenous,517mg/kg (517mg/kg),Journal of Pharmaceutical Sciences. Vol. 67, Pg. 566, 1978.
MSDS Information
ProviderLanguage
n-Hendecane English
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n-Hendecane Usage And Synthesis
Chemical Propertiescolourless liquid.
UsesPetroleum research, organic synthesis, distillation chaser.
UsesUndecane is used in preparation method of small-size hollow Silicon Dioxide.
UsesUndecane is mainly used as a model n-alkane in studies relating to viscosities, excess molar enthalpies and vapor-liquid equilibrium of binary alkane mixtures.
DefinitionChEBI: Undecane is a straight-chain alkane with 11 carbon atoms.
Production MethodsUndecane is obtained from the refining of petroleum. Paraffins are isolated by selective adsorption followed by fractional distillation to produce the desired mix of nparaffins (63).
Synthesis Reference(s)Journal of the American Chemical Society, 95, p. 6131, 1973 DOI: 10.1021/ja00799a058
The Journal of Organic Chemistry, 50, p. 3082, 1985
General DescriptionA colorless liquid. Insoluble in water and less dense than water. Flash point 130°F. Used to make other chemicals.
Air & Water ReactionsFlammable. Insoluble in water.
Reactivity ProfileSaturated aliphatic hydrocarbons, such as n-Hendecane, may be incompatible with strong oxidizing agents like nitric acid. Charring of the hydrocarbon may occur followed by ignition of unreacted hydrocarbon and other nearby combustibles. In other settings, aliphatic saturated hydrocarbons are mostly unreactive. They are not affected by aqueous solutions of acids, alkalis, most oxidizing agents, and most reducing agents.
Health HazardInhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Safety ProfileModerately toxic by intravenous route. Flammable liquid when exposed to heat, sparks, flame, or oxidizers.To fight fire, use foam, mist, dry chemical. Emitted from modern buildmg materials (CENEAR 69,22,91). When heated to decomposition it emits acrid smoke and irritating fumes. See also ALKANES.
CarcinogenicityUndecane (25 mg) and benzo[a] pyrene (B[a]P) (5 mg) were applied to the skin of female ICR/ Ha Swiss mice for 3/week for 440 days, inducing papillomas in 41 of 50 animals. B[a]P alone induced tumors in 12 of 50 animals in the same time, while undecane alone did not produce tumors.
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