2-Bromo-4'-methylacetophenone

2-Bromo-4'-methylacetophenone Basic information

Product Name:	2-Bromo-4'-methylacetophenone
Synonyms:	P-TOLYL ETHYL KETONE;ETHYL-P-TOLYLKETON;LABOTEST-BB LT00053050;2-Bromo-p-methylacetophenone;Acetophenone, 2-bromo-4'-methyl-;alpha-Bromo-4-methylacetophenone;alpha-Bromo-p-methylacetophenone;omega-Bromo-p-methylacetophenone
CAS:	619-41-0
MF:	C9H9BrO
MW:	213.07
EINECS:	210-595-0
Product Categories:	Aromatics;Acetophenone series;C9;Carbonyl Compounds;Ketones;Aromatic Acetophenones & Derivatives (substituted)
Mol File:	619-41-0.mol

2-Bromo-4'-methylacetophenone Chemical Properties

Melting point	45-49 °C(lit.)
Boiling point	238-239 °C(lit.)
density	0.993 g/mL at 25 °C(lit.)
refractive index	n20/D 1.528(lit.)
Fp	229 °F
storage temp.	2-8°C
solubility	Chloroform (Slightly), Ethyl Acetate
form	Crystalline Powder or Needles
color	White to light yellow
BRN	607041
Stability:	Stable. Incompatible with strong oxidizing agents, strong bases.
InChIKey	KRVGXFREOJHJAX-UHFFFAOYSA-N
CAS DataBase Reference	619-41-0(CAS DataBase Reference)
NIST Chemistry Reference	Ethanone, 2-bromo-1-(4-methylphenyl)-(619-41-0)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-27-37/39
RIDADR	UN 2811
WGK Germany	3
Hazard Note	Irritant
HazardClass	6.1
PackingGroup	III
HS Code	29147000

MSDS Information

Provider	Language
2-Bromo-1-(4-methylphenyl)ethan-1-one	English
SigmaAldrich	English
ACROS	English
ALFA	English

2-Bromo-4'-methylacetophenone Usage And Synthesis

Chemical Properties	White to light yellow crystal powder
Uses	2-Bromo-4′-methylacetophenone was used in the general fluorous thiol quenching method. It was also used in the preparation of hydroxyquinolinone and N-derivatized carboxamides.
General Description	2-Bromo-4′-methylacetophenone is an α-bromoketone.

2-Bromo-4'-methylacetophenone Preparation Products And Raw materials

Raw materials	Benzene, 1-methyl-4-[1-(phenylmethoxy)ethyl]--->(Z)-2-diazonio-1-(4-methylphenyl)ethenolate-->Benzenemethanol, α-(bromomethyl)-4-methyl--->Benzene, 1-(1-bromoethenyl)-4-methyl--->1-Bromo-2-(4-methylphenyl)acetylene-->4'-Methylacetophenone-->1-(4-Methylphenyl)ethanol-->4-Methylstyrene
Preparation Products	3-(4-METHYLPHENYL)ISOXAZOL-5-AMINE-->2-AMINO-4-(P-TOLYL)THIAZOLE-->1-(4-bromophenyl)-2-chloroethan-1-one-->3'-BROMO-4'-METHYLACETOPHENONE-->2,2-DIBROMO-1-P-TOLYLETHANONE

α-bromo-p-methylaceto-phenone ALPHA,ALPHA'-DIBROMO-2,5-DIMETHOXY-1,4-DIACETYLBENZENE 2,3-DIBROMO-1-(2,3,4,5,6-PENTAMETHYLPHENYL)-3-PHENYLPROPAN-1-ONE 2-bromo-3-methylacetophenone 2-bromo-1-(2,3,4,5,6-pentamethylphenyl)ethan-1-one 4,4'-Bis(2-bromoacetyl)biphenyl 2,3-DIBROMO-1-(4-METHYLPHENYL)-3-(2-THIENYL)PROPAN-1-ONE 4'-Bromo-2'-methylacetophenone 2-Bromoacetophenone 3'-BROMO-4'-METHYLACETOPHENONE 4-BROMO-3-METHYLACETOPHENONE[MFCD00045017] 4-(TERT-BUTYL)-2,6-DIMETHYL-3,5-DINITROPHENACYL BROMIDE 4'-BROMO-3'-METHYLACETOPHENONE 4-(Trifluoromethyl)phenacyl bromide 2-BROMO-1-(4-TERT-BUTYL-PHENYL)-ETHANONE 2-bromo-2-methylacetophenone PIPERACETAZINE (250 MG) 2-BROMO-3,3,6,8-TETRAMETHYL-1,2,3,4-TETRAHYDRONAPHTHALEN-1-ONE

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