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ALLYLMAGNESIUM BROMIDE

ALLYLMAGNESIUM BROMIDE Basic information
Product Name:ALLYLMAGNESIUM BROMIDE
Synonyms:ALLYLMAGNESIUM BROMIDE;Allylmagnesium bromide 1M solution in 2-MeTHF;Allylmagnesium bromide 1M solution in THF;Allylmagnesium bromide 1M solution in DEE;AllylMagnesiuM broMide, 1.0 M solution in diethyl ether, J&KSeal;AllylMagnesiuM broMide, 1.0 M solution in Diethyl ether, SpcSeal;AllylMagnesiuM broMide, 1.0 M solution in THF, SpcSeal;Allylmagnesium Bromide 1M ether solution
CAS:1730-25-2
MF:C3H5BrMg
MW:145.28
EINECS:217-046-4
Product Categories:Chemical Synthesis;Organometallic Reagents;grignard reagent;Grignard Reagents & Alkyl Metals;Classes of Metal Compounds;Grignard Reagents;Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;Alkyl;Grignard Reagents;Organometallic Reagents
Mol File:1730-25-2.mol
ALLYLMAGNESIUM BROMIDE Structure
ALLYLMAGNESIUM BROMIDE Chemical Properties
density 0.851 g/mL at 25 °C
Fp −40 °F
storage temp. Refrigerator
form Solution
color Yellow-green or gray
Sensitive air sensitive, moisture sensitive
BRN 969335
InChIKeyFEMBXICCJNZMMC-UHFFFAOYSA-M
CAS DataBase Reference1730-25-2
Safety Information
Hazard Codes F+,C,F
Risk Statements 12-14/15-19-22-34-66-67-11
Safety Statements 9-16-29-33-43-45-36/37/39-26
RIDADR UN 3399 4.3/PG 1
WGK Germany 1
F 1-3-10
HazardClass 8
PackingGroup III
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
ALLYLMAGNESIUM BROMIDE Usage And Synthesis
Chemical PropertiesYellow-green or grey liquid
UsesAllylmagnesium bromide solution can be used in the Grignard reaction, which is a key step to synthesize:
  • 2-(9,10-dihydro-9,10-propanoanthracen-9-yl)-N-methylethanamine (2), a homolog of benzoctamine
  • tarchonanthuslactone
  • (+)-preussin
  • polyhydroxylated quinolizidine alkaloids

ALLYLMAGNESIUM BROMIDE Preparation Products And Raw materials
Preparation Products3-METHYL-1,5-HEXADIENE-->7-Bromo-1-heptene-->1,8-NONADIENE-->Diisopropyl Allylboronate-->1,6-HEPTADIEN-4-OL-->(R)-(-)-PENTEN-2-OL-->2-Propene-1-sulfonyl chloride-->Tetraallyltin-->DIETHYL ALLYLPHOSPHONATE-->1,9-DECADIENE-->ALLYLOXYTRIMETHYLSILANE-->1,5-HEXADIENE
Allyltrimethylsilane 1-PROPYNYLMAGNESIUM BROMIDE 1-PROPENYLMAGNESIUM BROMIDE ISOBUTYLMAGNESIUM BROMIDE tert-buthylmagnesium bromide ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98 ISOPROPENYLMAGNESIUM BROMIDE Allyltriethylsilane SEC-BUTYLMAGNESIUM BROMIDE CYCLOPENTYLMAGNESIUM BROMIDE Cyclopropylmagnesium bromide ALLYLMAGNESIUM BROMIDE Allylmagnesium bromide,1,0-1,5ether Methylmagnesium Bromide Hydrogen bromide Magnesium nitrate hexahydrate Magnesium hydride Magnesium bromide
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